{"id":402256,"date":"2024-06-28T05:13:21","date_gmt":"2024-06-28T04:13:21","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/%e3%83%97%e3%83%ad%e3%82%bb%e3%82%b9%e5%b7%a5%e5%ad%a6%e3%81%ae%e3%81%9f%e3%82%81%e3%81%ae%e5%8c%96%e5%ad%a6%e7%86%b1%e5%8a%9b%e5%ad%a6\/"},"modified":"2024-06-28T05:13:21","modified_gmt":"2024-06-28T04:13:21","slug":"%e3%83%97%e3%83%ad%e3%82%bb%e3%82%b9%e5%b7%a5%e5%ad%a6%e3%81%ae%e3%81%9f%e3%82%81%e3%81%ae%e5%8c%96%e5%ad%a6%e7%86%b1%e5%8a%9b%e5%ad%a6","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/ja\/%e3%83%97%e3%83%ad%e3%82%bb%e3%82%b9%e5%b7%a5%e5%ad%a6%e3%81%ae%e3%81%9f%e3%82%81%e3%81%ae%e5%8c%96%e5%ad%a6%e7%86%b1%e5%8a%9b%e5%ad%a6\/","title":{"rendered":"\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u305f\u3081\u306e\u5316\u5b66\u71b1\u529b\u5b66"},"content":{"rendered":"<p class=\"sidekick\">\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u305f\u3081\u306e\u5316\u5b66\u71b1\u529b\u5b66\u3002\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316\u3001\u57fa\u672c\u6cd5\u5247\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3001\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u3001\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306b\u3064\u3044\u3066\u89e3\u8aac\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/06\/\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u305f\u3081\u306e\u5316\u5b66\u71b1\u529b\u5b66.png\" alt=\"\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u305f\u3081\u306e\u5316\u5b66\u71b1\u529b\u5b66\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u305f\u3081\u306e\u5316\u5b66\u71b1\u529b\u5b66<\/h2>\n<p>\u5316\u5b66\u71b1\u529b\u5b66\u306f\u3001\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u57fa\u790e\u3068\u306a\u308b\u91cd\u8981\u306a\u5206\u91ce\u3067\u3059\u3002\u5316\u5b66\u71b1\u529b\u5b66\u3092\u7406\u89e3\u3059\u308b\u3053\u3068\u3067\u3001\u5316\u5b66\u53cd\u5fdc\u304c\u3069\u306e\u3088\u3046\u306b\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u5909\u5316\u3055\u305b\u308b\u304b\u3001\u305d\u3057\u3066\u305d\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5909\u5316\u304c\u30b7\u30b9\u30c6\u30e0\u5168\u4f53\u306b\u3069\u306e\u3088\u3046\u306b\u5f71\u97ff\u3059\u308b\u304b\u3092\u628a\u63e1\u3067\u304d\u307e\u3059\u3002\u4ee5\u4e0b\u3067\u306f\u3001\u5316\u5b66\u71b1\u529b\u5b66\u306e\u57fa\u672c\u6982\u5ff5\u306b\u3064\u3044\u3066\u8aac\u660e\u3057\u307e\u3059\u3002<\/p>\n<h2>\u71b1\u529b\u5b66\u306e\u57fa\u672c\u6cd5\u5247<\/h2>\n<p>\u71b1\u529b\u5b66\u306b\u306f4\u3064\u306e\u57fa\u672c\u6cd5\u5247\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<p><u1><\/p>\n<li><b>\u30bc\u30ed\u6cd5\u5247:<\/b> \u3082\u3057\u7269\u4f53A\u3068\u7269\u4f53B\u304c\u71b1\u5e73\u8861\u306b\u3042\u308a\u3001\u7269\u4f53B\u3068\u7269\u4f53C\u3082\u71b1\u5e73\u8861\u306b\u3042\u308b\u306a\u3089\u3001\u7269\u4f53A\u3068\u7269\u4f53C\u3082\u71b1\u5e73\u8861\u306b\u3042\u308a\u307e\u3059\u3002<\/li>\n<li><b>\u7b2c\u4e00\u6cd5\u5247:<\/b> \u30a8\u30cd\u30eb\u30ae\u30fc\u4fdd\u5b58\u306e\u6cd5\u5247\u3002\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u5f62\u3092\u5909\u3048\u3066\u3082\u6d88\u6ec5\u305b\u305a\u3001\u5168\u4f53\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u4e00\u5b9a\u3067\u3059\u3002<\/li>\n<li><b>\u7b2c\u4e8c\u6cd5\u5247:<\/b> \u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u5897\u5927\u306e\u6cd5\u5247\u3002\u9589\u3058\u305f\u7cfb\u306e\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\uff08\u4e0d\u898f\u5247\u6027\uff09\u306f\u5e38\u306b\u5897\u5927\u3059\u308b\u50be\u5411\u306b\u3042\u308a\u307e\u3059\u3002<\/li>\n<li><b>\u7b2c\u4e09\u6cd5\u5247:<\/b> \u7d76\u5bfe\u96f6\u5ea6\u306b\u8fd1\u3065\u304f\u3068\u3001\u7cfb\u306e\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306f\u4e00\u5b9a\u306e\u5024\u306b\u8fd1\u3065\u304d\u307e\u3059\u3002<\/li>\n<p><\/u1><\/p>\n<h2>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc<\/h2>\n<p>\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u3067\u91cd\u8981\u306a\u6982\u5ff5\u306e\u4e00\u3064\u306b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc (G) \u304c\u3042\u308a\u307e\u3059\u3002\u3053\u308c\u306f\u4ee5\u4e0b\u306e\u3088\u3046\u306a\u5f0f\u3067\u8868\u3055\u308c\u307e\u3059\u3002<\/p>\n<p><i>G = H &#8211; TS<\/i><\/p>\n<p>\u3053\u3053\u3067\u3001<i>H<\/i> \u306f\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u3001<i>T<\/i> \u306f\u6e29\u5ea6\u3001<i>S<\/i> \u306f\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3067\u3059\u3002\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u8ca0\u306e\u5024\u3092\u6301\u3064\u3068\u304d\u3001\u5316\u5b66\u53cd\u5fdc\u306f\u81ea\u767a\u7684\u306b\u9032\u884c\u3057\u307e\u3059\u3002<\/p>\n<h2>\u53cd\u5fdc\u306e\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u5909\u5316<\/h2>\n<p>\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u5909\u5316 (\u0394H) \u306f\u3001\u751f\u6210\u7269\u306e\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u3068\u53cd\u5fdc\u7269\u306e\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u3068\u306e\u5dee\u3067\u8868\u3055\u308c\u307e\u3059\u3002<\/p>\n<p> \u0394H = H<sub>\u751f\u6210\u7269<\/sub> &#8211; H<sub>\u53cd\u5fdc\u7269<\/sub> <\/p>\n<p> \u0394H \u304c\u8ca0\u306e\u5834\u5408\u3001\u53cd\u5fdc\u306f\u767a\u71b1\u53cd\u5fdc\u3067\u3042\u308a\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u653e\u51fa\u3055\u308c\u307e\u3059\u3002\u9006\u306b\u3001\u0394H \u304c\u6b63\u306e\u5834\u5408\u3001\u53cd\u5fdc\u306f\u5438\u71b1\u53cd\u5fdc\u3067\u3042\u308a\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u5438\u53ce\u3057\u307e\u3059\u3002<\/p>\n<h2>\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3068\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u5909\u5316<\/h2>\n<p>\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc (S) \u306f\u3001\u7cfb\u306e\u30e9\u30f3\u30c0\u30e0\u6027\u3084\u4e0d\u898f\u5247\u6027\u3092\u8868\u3059\u91cf\u3067\u3059\u3002\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u5909\u5316 (\u0394S) \u306f\u4ee5\u4e0b\u306e\u3088\u3046\u306b\u8868\u3055\u308c\u307e\u3059\u3002<\/p>\n<p> \u0394S = S<sub>\u751f\u6210\u7269<\/sub> &#8211; S<sub>\u53cd\u5fdc\u7269<\/sub> <\/p>\n<p>\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u3067\u306f\u3001\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u5909\u5316\u3092\u7406\u89e3\u3059\u308b\u3053\u3068\u3067\u3001\u53cd\u5fdc\u304c\u3069\u306e\u7a0b\u5ea6\u81ea\u7136\u306b\u9032\u884c\u3059\u308b\u304b\u3092\u8a55\u4fa1\u3067\u304d\u307e\u3059\u3002<\/p>\n<h2>\u5e73\u8861\u5b9a\u6570\u3068\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc<\/h2>\n<p>\u5316\u5b66\u53cd\u5fdc\u304c\u5316\u5b66\u5e73\u8861\u306b\u3042\u308b\u3068\u304d\u306e\u5e73\u8861\u5b9a\u6570 (K) \u306f\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316 (\u0394G) \u306b\u95a2\u4fc2\u3057\u3066\u3044\u307e\u3059\u3002\u3053\u306e\u95a2\u4fc2\u306f\u4ee5\u4e0b\u306e\u5f0f\u3067\u8868\u3055\u308c\u307e\u3059:<\/p>\n<p> \u0394G = -RT ln(K) <\/p>\n<p>\u3053\u3053\u3067\u3001<i>R<\/i> \u306f\u6c17\u4f53\u5b9a\u6570\u3001<i>T<\/i> \u306f\u7d76\u5bfe\u6e29\u5ea6\u3067\u3059\u3002\u5e73\u8861\u5b9a\u6570 K \u304c\u5927\u304d\u3044\u307b\u3069\u3001\u53cd\u5fdc\u306f\u53f3\u306b\u9032\u884c\u3057\u3084\u3059\u304f\u306a\u308a\u307e\u3059\u3002<\/p>\n<h2>\u307e\u3068\u3081<\/h2>\n<p>\u5316\u5b66\u71b1\u529b\u5b66\u306f\u3001\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306b\u304a\u3051\u308b\u5316\u5b66\u53cd\u5fdc\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316\u3092\u7406\u89e3\u3059\u308b\u305f\u3081\u306e\u57fa\u672c\u3068\u306a\u308a\u307e\u3059\u3002\u71b1\u529b\u5b66\u306e\u57fa\u672c\u6cd5\u5247\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3001\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u5909\u5316\u3001\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3001\u305d\u3057\u3066\u5e73\u8861\u5b9a\u6570\u306f\u3001\u3059\u3079\u3066\u304c\u5bc6\u63a5\u306b\u95a2\u9023\u3057\u3066\u304a\u308a\u3001\u3053\u308c\u3089\u306e\u6982\u5ff5\u3092\u7406\u89e3\u3059\u308b\u3053\u3068\u3067\u3001\u3088\u308a\u52b9\u7387\u7684\u306a\u5316\u5b66\u30d7\u30ed\u30bb\u30b9\u306e\u8a2d\u8a08\u3068\u904b\u7528\u304c\u53ef\u80fd\u306b\u306a\u308a\u307e\u3059\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u30d7\u30ed\u30bb\u30b9\u5de5\u5b66\u306e\u305f\u3081\u306e\u5316\u5b66\u71b1\u529b\u5b66\u3002\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316\u3001\u57fa\u672c\u6cd5\u5247\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3001\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u3001\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306b\u3064\u3044\u3066\u89e3\u8aac\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[125],"tags":[],"yoast_head":"<!-- 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