{"id":402410,"date":"2024-06-28T05:14:23","date_gmt":"2024-06-28T04:14:23","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/%e5%8c%96%e5%ad%a6%e3%81%ab%e3%81%8a%e3%81%91%e3%82%8b%e3%82%ae%e3%83%96%e3%82%ba%e8%87%aa%e7%94%b1%e3%82%a8%e3%83%8d%e3%83%ab%e3%82%ae%e3%83%bc%e3%81%ae%e5%bf%9c%e7%94%a8\/"},"modified":"2024-06-28T05:14:23","modified_gmt":"2024-06-28T04:14:23","slug":"%e5%8c%96%e5%ad%a6%e3%81%ab%e3%81%8a%e3%81%91%e3%82%8b%e3%82%ae%e3%83%96%e3%82%ba%e8%87%aa%e7%94%b1%e3%82%a8%e3%83%8d%e3%83%ab%e3%82%ae%e3%83%bc%e3%81%ae%e5%bf%9c%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/ja\/%e5%8c%96%e5%ad%a6%e3%81%ab%e3%81%8a%e3%81%91%e3%82%8b%e3%82%ae%e3%83%96%e3%82%ba%e8%87%aa%e7%94%b1%e3%82%a8%e3%83%8d%e3%83%ab%e3%82%ae%e3%83%bc%e3%81%ae%e5%bf%9c%e7%94%a8\/","title":{"rendered":"\u5316\u5b66\u306b\u304a\u3051\u308b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5fdc\u7528"},"content":{"rendered":"<p class=\"sidekick\">\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u306e\u81ea\u767a\u6027\u3084\u5e73\u8861\u72b6\u614b\u3001\u96fb\u6c60\u306e\u8d77\u96fb\u529b\u3001\u53cd\u5fdc\u901f\u5ea6\u3092\u4e88\u6e2c\u3059\u308b\u305f\u3081\u306e\u91cd\u8981\u306a\u7269\u7406\u91cf\u3067\u3059\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/06\/\u5316\u5b66\u306b\u304a\u3051\u308b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5fdc\u7528.png\" alt=\"\u5316\u5b66\u306b\u304a\u3051\u308b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5fdc\u7528\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u5316\u5b66\u306b\u304a\u3051\u308b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5fdc\u7528<\/h2>\n<p>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u5316\u5b66\u306b\u304a\u3044\u3066\u975e\u5e38\u306b\u91cd\u8981\u306a\u6982\u5ff5\u3067\u3042\u308a\u3001\u591a\u304f\u306e\u53cd\u5fdc\u3084\u30d7\u30ed\u30bb\u30b9\u306e\u7406\u89e3\u306b\u5f79\u7acb\u3061\u307e\u3059\u3002\u3053\u306e\u7269\u7406\u91cf\u306f\u3001\u4e00\u5b9a\u6e29\u5ea6\u304a\u3088\u3073\u5727\u529b\u4e0b\u3067\u306e\u7cfb\u306e\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316\u3092\u793a\u3057\u3001\u305d\u306e\u8a18\u53f7\u306f \\( G \\) \u3067\u8868\u3055\u308c\u307e\u3059\u3002\u4ee5\u4e0b\u3067\u306f\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u57fa\u672c\u6982\u5ff5\u3068\u305d\u306e\u5fdc\u7528\u306b\u3064\u3044\u3066\u8aac\u660e\u3057\u307e\u3059\u3002<\/p>\n<h2>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u57fa\u672c<\/h2>\n<p>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u4ee5\u4e0b\u306e\u95a2\u4fc2\u5f0f\u3067\u5b9a\u7fa9\u3055\u308c\u307e\u3059\uff1a<\/p>\n<p>\n\\[ G = H &#8211; TS \\]\n<\/p>\n<p>\u3053\u3053\u3067\u3001<\/p>\n<ul>\n<li>\\(G\\)\uff1a\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc<\/li>\n<li>\\(H\\)\uff1a\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\uff08\u7cfb\u306e\u5168\u30a8\u30cd\u30eb\u30ae\u30fc\uff09<\/li>\n<li>\\(T\\)\uff1a\u7d76\u5bfe\u6e29\u5ea6\uff08\u30b1\u30eb\u30d3\u30f3\u5358\u4f4d\uff09<\/li>\n<li>\\(S\\)\uff1a\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\uff08\u4e71\u96d1\u3055\u306e\u5c3a\u5ea6\uff09<\/li>\n<\/ul>\n<p>\u3053\u306e\u5f0f\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u304c\u81ea\u767a\u7684\u306b\u9032\u884c\u3059\u308b\u304b\u3069\u3046\u304b\u3092\u4e88\u6e2c\u3059\u308b\u306e\u306b\u91cd\u8981\u3067\u3059\u3002\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316 \\(\\Delta G\\) \u304c\u8ca0\u306e\u5024\u3067\u3042\u308c\u3070\u3001\u53cd\u5fdc\u306f\u81ea\u767a\u7684\u306b\u9032\u884c\u3057\u307e\u3059\u3002\u6b63\u306e\u5024\u3067\u3042\u308c\u3070\u975e\u81ea\u767a\u7684\u30010\u3067\u3042\u308c\u3070\u5e73\u8861\u72b6\u614b\u306b\u3042\u308a\u307e\u3059\u3002<\/p>\n<h2>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u5fdc\u7528<\/h2>\n<p>\u4ee5\u4e0b\u306f\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u5316\u5b66\u306b\u304a\u3044\u3066\u3069\u306e\u3088\u3046\u306b\u6d3b\u7528\u3055\u308c\u308b\u304b\u306e\u5177\u4f53\u4f8b\u3067\u3059\uff1a<\/p>\n<h3>\u5316\u5b66\u5e73\u8861<\/h3>\n<p>\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3044\u3066\u3001\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u5e73\u8861\u72b6\u614b\u3092\u6c7a\u5b9a\u3059\u308b\u305f\u3081\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u5e73\u8861\u5b9a\u6570 \\( K \\) \u306f\u6b21\u306e\u3088\u3046\u306b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3068\u7d50\u3073\u3064\u3051\u3089\u308c\u307e\u3059\uff1a<\/p>\n<p>\n\\[ \\Delta G^\\circ = -RT \\ln K \\]\n<\/p>\n<p>\u3053\u3053\u3067\u3001<\/p>\n<ul>\n<li>\\(\\Delta G^\\circ\\)\uff1a\u6a19\u6e96\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316<\/li>\n<li>\\(R\\)\uff1a\u6c17\u4f53\u5b9a\u6570<\/li>\n<li>\\(T\\)\uff1a\u7d76\u5bfe\u6e29\u5ea6<\/li>\n<li>\\(K\\)\uff1a\u5e73\u8861\u5b9a\u6570<\/li>\n<\/ul>\n<p>\u3053\u306e\u95a2\u4fc2\u5f0f\u3092\u4f7f\u7528\u3059\u308b\u3053\u3068\u3067\u3001\u53cd\u5fdc\u7269\u3068\u751f\u6210\u7269\u306e\u6fc3\u5ea6\u914d\u5206\u3092\u4e88\u6e2c\u3067\u304d\u307e\u3059\u3002<\/p>\n<h3>\u96fb\u6c60\u3068\u96fb\u6c17\u5316\u5b66<\/h3>\n<p>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316\u306f\u3001\u96fb\u6c60\u306e\u8d77\u96fb\u529b\uff08\u96fb\u6c60\u96fb\u5727\uff09\u3092\u8a08\u7b97\u3059\u308b\u306e\u306b\u3082\u5f79\u7acb\u3061\u307e\u3059\u3002\u96fb\u6c60\u53cd\u5fdc\u306b\u5bfe\u3059\u308b\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316 \\(\\Delta G\\) \u3068\u96fb\u6c60\u96fb\u5727\uff08\u6a19\u6e96\u96fb\u6c60\u96fb\u5727\uff09\\( E^\\circ \\) \u306f\u6b21\u306e\u5f0f\u3067\u95a2\u9023\u4ed8\u3051\u3089\u308c\u307e\u3059\uff1a<\/p>\n<p>\n\\[ \\Delta G = -nFE^\\circ \\]\n<\/p>\n<p>\u3053\u3053\u3067\u3001<\/p>\n<ul>\n<li>\\(n\\)\uff1a\u96fb\u5b50\u306e\u30e2\u30eb\u6570<\/li>\n<li>\\(F\\)\uff1a\u30d5\u30a1\u30e9\u30c7\u30fc\u5b9a\u6570<\/li>\n<li>\\(E^\\circ\\)\uff1a\u6a19\u6e96\u96fb\u6c60\u96fb\u5727<\/li>\n<\/ul>\n<h3>\u53cd\u5fdc\u901f\u5ea6<\/h3>\n<p>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u53cd\u5fdc\u901f\u5ea6\u8ad6\u3067\u3082\u91cd\u8981\u306a\u5f79\u5272\u3092\u679c\u305f\u3057\u307e\u3059\u3002\u53cd\u5fdc\u306e\u6d3b\u6027\u5316\u30a8\u30cd\u30eb\u30ae\u30fc\u3068\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u969c\u58c1\u306f\u3001\u3069\u308c\u3060\u3051\u65e9\u304f\u53cd\u5fdc\u304c\u9032\u884c\u3059\u308b\u304b\u3092\u6c7a\u5b9a\u3057\u307e\u3059\u3002<\/p>\n<h2>\u307e\u3068\u3081<\/h2>\n<p>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u591a\u304f\u306e\u5316\u5b66\u53cd\u5fdc\u3084\u30d7\u30ed\u30bb\u30b9\u3092\u7406\u89e3\u3057\u3001\u4e88\u6e2c\u3059\u308b\u305f\u3081\u306e\u91cd\u8981\u306a\u30c4\u30fc\u30eb\u3067\u3059\u3002\u53cd\u5fdc\u306e\u81ea\u767a\u6027\u3001\u5e73\u8861\u72b6\u614b\u3001\u96fb\u6c60\u8d77\u96fb\u529b\u3001\u53cd\u5fdc\u901f\u5ea6\u306a\u3069\u3001\u3055\u307e\u3056\u307e\u306a\u9762\u3067\u305d\u306e\u5fdc\u7528\u304c\u898b\u3089\u308c\u307e\u3059\u3002\u7406\u89e3\u3092\u6df1\u3081\u308b\u3053\u3068\u3067\u3001\u5316\u5b66\u306e\u591a\u304f\u306e\u73fe\u8c61\u3092\u3088\u308a\u3088\u304f\u7406\u89e3\u3057\u3001\u4e88\u6e2c\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u306b\u306a\u308a\u307e\u3059\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u306e\u81ea\u767a\u6027\u3084\u5e73\u8861\u72b6\u614b\u3001\u96fb\u6c60\u306e\u8d77\u96fb\u529b\u3001\u53cd\u5fdc\u901f\u5ea6\u3092\u4e88\u6e2c\u3059\u308b\u305f\u3081\u306e\u91cd\u8981\u306a\u7269\u7406\u91cf\u3067\u3059\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[125],"tags":[],"yoast_head":"<!-- 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