{"id":403950,"date":"2024-06-28T05:24:35","date_gmt":"2024-06-28T04:24:35","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/%e8%b6%85%e4%bc%9d%e5%b0%8e%e6%9d%90%e6%96%99%e3%81%ae%e7%86%b1%e5%8a%9b%e5%ad%a6\/"},"modified":"2024-06-28T05:24:35","modified_gmt":"2024-06-28T04:24:35","slug":"%e8%b6%85%e4%bc%9d%e5%b0%8e%e6%9d%90%e6%96%99%e3%81%ae%e7%86%b1%e5%8a%9b%e5%ad%a6","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/ja\/%e8%b6%85%e4%bc%9d%e5%b0%8e%e6%9d%90%e6%96%99%e3%81%ae%e7%86%b1%e5%8a%9b%e5%ad%a6\/","title":{"rendered":"\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u71b1\u529b\u5b66"},"content":{"rendered":"<p class=\"sidekick\">\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u7279\u6027\u3001\u6b74\u53f2\u3001\u30e1\u30ab\u30cb\u30ba\u30e0\u3001\u71b1\u529b\u5b66\u7684\u6027\u8cea\u3001\u5fdc\u7528\u4f8b\u3092\u89e3\u8aac\u3057\u305f\u8a18\u4e8b\u3067\u3059\u3002\u8d85\u4f1d\u5c0e\u306e\u57fa\u672c\u539f\u7406\u3084\u95a2\u9023\u3059\u308b\u71b1\u529b\u5b66\u7406\u8ad6\u3092\u7d39\u4ecb\u3057\u307e\u3059\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/06\/\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u71b1\u529b\u5b66.png\" alt=\"\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u71b1\u529b\u5b66\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u71b1\u529b\u5b66<\/h2>\n<p>\u8d85\u4f1d\u5c0e\u6750\u6599\u306f\u3001\u4f4e\u6e29\u3067\u96fb\u6c17\u62b5\u6297\u304c\u30bc\u30ed\u306b\u306a\u308b\u7279\u6027\u3092\u6301\u3064\u7269\u8cea\u3067\u3059\u3002\u3053\u306e\u73fe\u8c61\u306f\u8d85\u4f1d\u5c0e\u3068\u547c\u3070\u308c\u3001\u9a5a\u7570\u7684\u306a\u7269\u7406\u7684\u73fe\u8c61\u306e\u4e00\u3064\u3068\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u8d85\u4f1d\u5c0e\u306f1911\u5e74\u306b\u30aa\u30e9\u30f3\u30c0\u306e\u7269\u7406\u5b66\u8005\u30d8\u30a4\u30af\u30fb\u30ab\u30e1\u30eb\u30ea\u30f3\u30b0\u30fb\u30aa\u30cd\u30b9\u306b\u3088\u3063\u3066\u767a\u898b\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<h2>\u8d85\u4f1d\u5c0e\u306e\u57fa\u672c\u539f\u7406<\/h2>\n<p>\u8d85\u4f1d\u5c0e\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u3092\u7406\u89e3\u3059\u308b\u305f\u3081\u306b\u3001\u307e\u305a\u306f\u8d85\u4f1d\u5c0e\u8ee2\u79fb\u6e29\u5ea6\uff08<i>Critical Temperature<\/i>\u307e\u305f\u306fT<sub>c<\/sub>\uff09\u306b\u3064\u3044\u3066\u8aac\u660e\u3057\u307e\u3059\u3002T<sub>c<\/sub>\u3068\u306f\u3001\u3042\u308b\u6e29\u5ea6\u4ee5\u4e0b\u306b\u306a\u308b\u3068\u7269\u8cea\u304c\u8d85\u4f1d\u5c0e\u72b6\u614b\u306b\u79fb\u884c\u3059\u308b\u6e29\u5ea6\u3092\u6307\u3057\u307e\u3059\u3002\u591a\u304f\u306e\u4f1d\u7d71\u7684\u306a\u8d85\u4f1d\u5c0e\u6750\u6599\u306f\u975e\u5e38\u306b\u4f4e\u3044\u6e29\u5ea6\uff08\u6570\u30b1\u30eb\u30d3\u30f3\uff09\u3067\u8d85\u4f1d\u5c0e\u72b6\u614b\u306b\u306a\u308a\u307e\u3059\u304c\u3001\u9ad8\u6e29\u8d85\u4f1d\u5c0e\u6750\u6599\u306f\u6bd4\u8f03\u7684\u9ad8\u3044\u6e29\u5ea6\u3067\u8d85\u4f1d\u5c0e\u3092\u793a\u3057\u307e\u3059\u3002<\/p>\n<h2>\u30a8\u30cd\u30eb\u30ae\u30fc\u30ae\u30e3\u30c3\u30d7\u3068\u30af\u30fc\u30d1\u30fc\u5bfe<\/h2>\n<p>\u8d85\u4f1d\u5c0e\u72b6\u614b\u306b\u306a\u308b\u3068\u3001\u6750\u6599\u5185\u306e\u96fb\u5b50\u306f\u30af\u30fc\u30d1\u30fc\u5bfe\u3068\u547c\u3070\u308c\u308b\u30da\u30a2\u3092\u5f62\u6210\u3057\u307e\u3059\u3002\u30af\u30fc\u30d1\u30fc\u5bfe\u306f\u30d5\u30a7\u30eb\u30df\u9762\u4e0a\u3067\u5bfe\u306b\u306a\u308a\u3001\u96c6\u56e3\u7684\u306b\u51dd\u7e2e\u3057\u307e\u3059\u3002\u3053\u306e\u3068\u304d\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u30ae\u30e3\u30c3\u30d7\u0394\u304c\u5f62\u6210\u3055\u308c\u3001\u96fb\u5b50\u306f\u901a\u5e38\u306e\u6563\u4e71\u30d7\u30ed\u30bb\u30b9\u3092\u53d7\u3051\u306a\u304f\u306a\u308a\u307e\u3059\u3002<\/p>\n<ul>\n<li>\u30af\u30fc\u30d1\u30fc\u5bfe\u306e\u7279\u5fb4\uff1a\u96fb\u5b50\u540c\u58eb\u304c\u5f15\u304d\u5408\u3046\u3053\u3068\u3067\u30da\u30a2\u3092\u5f62\u6210\u3002<\/li>\n<li>\u30a8\u30cd\u30eb\u30ae\u30fc\u30ae\u30e3\u30c3\u30d7\uff1a\u8d85\u4f1d\u5c0e\u72b6\u614b\u3078\u306e\u9077\u79fb\u306b\u4f34\u3044\u5f62\u6210\u3055\u308c\u308b\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5dee\u3002<\/li>\n<\/ul>\n<h2>\u71b1\u529b\u5b66\u3068\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc<\/h2>\n<p>\u8d85\u4f1d\u5c0e\u72b6\u614b\u306e\u71b1\u529b\u5b66\u3092\u7406\u89e3\u3059\u308b\u305f\u3081\u306b\u3001\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\uff08Gibbs Free Energy\uff09\u6982\u5ff5\u304c\u91cd\u8981\u3067\u3059\u3002\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5dee\u0394G\u306f\u3001\u8d85\u4f1d\u5c0e\u72b6\u614b\u3068\u901a\u5e38\u72b6\u614b\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u5dee\u3092\u8868\u3057\u307e\u3059\u3002<\/p>\n<p>\u8d85\u4f1d\u5c0e\u72b6\u614b\u306e\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u4ee5\u4e0b\u306e\u3088\u3046\u306b\u8868\u3055\u308c\u307e\u3059\u3002<\/p>\n<p>\\[ G_s = G_n &#8211; \\frac{1}{2}N(0)\\Delta^2 \\]\n<p>\u3053\u3053\u3067\u3001G<sub>s<\/sub>\u306f\u8d85\u4f1d\u5c0e\u72b6\u614b\u306e\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3001G<sub>n<\/sub>\u306f\u901a\u5e38\u72b6\u614b\u306e\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3001N(0)\u306f\u30d5\u30a7\u30eb\u30df\u9762\u4e0a\u306e\u72b6\u614b\u5bc6\u5ea6\u3067\u3059\u3002<\/p>\n<h2>\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3068\u6bd4\u71b1<\/h2>\n<p>\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\uff08S\uff09\u3068\u6bd4\u71b1\uff08C\uff09\u3082\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u91cd\u8981\u306a\u71b1\u529b\u5b66\u7684\u6027\u8cea\u3067\u3059\u3002\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306e\u5909\u5316\u0394S\u306f\u3001\u8d85\u4f1d\u5c0e\u72b6\u614b\u3068\u901a\u5e38\u72b6\u614b\u306e\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306e\u5dee\u3092\u8868\u3057\u3001\u4ee5\u4e0b\u306e\u3088\u3046\u306b\u66f8\u3051\u307e\u3059\u3002<\/p>\n<p>\\[ \\Delta S = -\\frac{\\partial \\Delta G}{\\partial T} \\]\n<p>\u307e\u305f\u3001\u6bd4\u71b1C\u306f\u6b21\u306e\u3088\u3046\u306b\u5b9a\u7fa9\u3055\u308c\u307e\u3059\u3002<\/p>\n<p>\\[ C = T \\frac{\\partial S}{\\partial T} \\]\n<p>\u8d85\u4f1d\u5c0e\u72b6\u614b\u3067\u306f\u30a8\u30cd\u30eb\u30ae\u30fc\u30ae\u30e3\u30c3\u30d7\u306e\u5b58\u5728\u306b\u3088\u308a\u3001\u6bd4\u71b1\u306f\u901a\u5e38\u72b6\u614b\u3068\u306f\u7570\u306a\u308a\u3001\u7279\u5fb4\u7684\u306a\u632f\u308b\u821e\u3044\u3092\u793a\u3057\u307e\u3059\u3002<\/p>\n<h2>\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u5fdc\u7528<\/h2>\n<p>\u8d85\u4f1d\u5c0e\u6750\u6599\u306f\u533b\u5b66\u30fb\u79d1\u5b66\u6280\u8853\u30fb\u96fb\u529b\u7523\u696d\u306a\u3069\u591a\u5c90\u306b\u308f\u305f\u308b\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u3066\u3044\u307e\u3059\u3002MRI\u88c5\u7f6e\u3084\u7c92\u5b50\u52a0\u901f\u5668\u3001\u8d85\u4f1d\u5c0e\u78c1\u6c17\u6d6e\u4e0a\u5217\u8eca\u306a\u3069\u306b\u5229\u7528\u3055\u308c\u3066\u304a\u308a\u3001\u5c06\u6765\u7684\u306a\u7701\u30a8\u30cd\u30eb\u30ae\u30fc\u6280\u8853\u3068\u3057\u3066\u3082\u91cd\u8981\u8996\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<h2>\u307e\u3068\u3081<\/h2>\n<p>\u8d85\u4f1d\u5c0e\u6750\u6599\u306f\u305d\u306e\u30e6\u30cb\u30fc\u30af\u306a\u7279\u6027\u306b\u3088\u308a\u3001\u3055\u307e\u3056\u307e\u306a\u5fdc\u7528\u53ef\u80fd\u6027\u3092\u6301\u3064\u4e00\u65b9\u3067\u3001\u305d\u306e\u71b1\u529b\u5b66\u7684\u6027\u8cea\u306e\u7406\u89e3\u306f\u672a\u3060\u9032\u884c\u4e2d\u3067\u3059\u3002\u4eca\u5f8c\u306e\u7814\u7a76\u304c\u9032\u3080\u3053\u3068\u3067\u3001\u66f4\u306a\u308b\u6280\u8853\u7684\u767a\u5c55\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8d85\u4f1d\u5c0e\u6750\u6599\u306e\u7279\u6027\u3001\u6b74\u53f2\u3001\u30e1\u30ab\u30cb\u30ba\u30e0\u3001\u71b1\u529b\u5b66\u7684\u6027\u8cea\u3001\u5fdc\u7528\u4f8b\u3092\u89e3\u8aac\u3057\u305f\u8a18\u4e8b\u3067\u3059\u3002\u8d85\u4f1d\u5c0e\u306e\u57fa\u672c\u539f\u7406\u3084\u95a2\u9023\u3059\u308b\u71b1\u529b\u5b66\u7406\u8ad6\u3092\u7d39\u4ecb\u3057\u307e\u3059\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[125],"tags":[],"yoast_head":"<!-- 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