{"id":404412,"date":"2024-06-28T05:27:35","date_gmt":"2024-06-28T04:27:35","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/%e9%9b%bb%e6%b0%97%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%bf%9c%e3%81%ae%e7%86%b1%e5%8a%9b%e5%ad%a6\/"},"modified":"2024-06-28T05:27:35","modified_gmt":"2024-06-28T04:27:35","slug":"%e9%9b%bb%e6%b0%97%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%bf%9c%e3%81%ae%e7%86%b1%e5%8a%9b%e5%ad%a6","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/ja\/%e9%9b%bb%e6%b0%97%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%bf%9c%e3%81%ae%e7%86%b1%e5%8a%9b%e5%ad%a6\/","title":{"rendered":"\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66"},"content":{"rendered":"<p class=\"sidekick\">\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\u306b\u3064\u3044\u3066\u57fa\u672c\u6982\u5ff5\u304b\u3089\u30cd\u30eb\u30f3\u30b9\u30c8\u65b9\u7a0b\u5f0f\u3001\u96fb\u6c60\u306e\u52b9\u7387\u307e\u3067\u3092\u521d\u5fc3\u8005\u5411\u3051\u306b\u89e3\u8aac\u3002\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\u306e\u7406\u89e3\u306b\u6700\u9069\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/06\/\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66.png\" alt=\"\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66<\/h2>\n<p>\n\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u3068\u306f\u3001\u96fb\u6c17\u30a8\u30cd\u30eb\u30ae\u30fc\u3068\u5316\u5b66\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u76f8\u4e92\u306b\u5909\u63db\u3055\u308c\u308b\u53cd\u5fdc\u306e\u3053\u3068\u3067\u3059\u3002\u7279\u306b\u3001\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\u306f\u3001\u3053\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\u304c\u3069\u306e\u3088\u3046\u306b\u884c\u308f\u308c\u308b\u306e\u304b\u3092\u7406\u89e3\u3059\u308b\u305f\u3081\u306e\u57fa\u76e4\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002\u672c\u8a18\u4e8b\u3067\u306f\u3001\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u71b1\u529b\u5b66\u306e\u57fa\u672c\u7684\u306a\u6982\u5ff5\u3092\u521d\u5fc3\u8005\u5411\u3051\u306b\u89e3\u8aac\u3057\u307e\u3059\u3002\n<\/p>\n<h2>\u57fa\u672c\u6982\u5ff5<\/h2>\n<ul>\n<li><b>\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc (G)<\/b>: \u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u3001\u30b7\u30b9\u30c6\u30e0\u304c\u884c\u3046\u3053\u3068\u304c\u3067\u304d\u308b\u6700\u5927\u306e\u4ed5\u4e8b\u91cf\u3092\u793a\u3059\u6307\u6a19\u3067\u3059\u3002\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc (G) \u306f\u4ee5\u4e0b\u306e\u5f0f\u3067\u8868\u3055\u308c\u307e\u3059:<br \/>\n        <br \/> G = H &#8211; TS<br \/>\n        <br \/> \u3053\u3053\u3067\u3001H \u306f\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u3001T \u306f\u7d76\u5bfe\u6e29\u5ea6\u3001S \u306f\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u3067\u3059\u3002\n    <\/li>\n<li><b>\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc (H)<\/b>: \u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u306f\u30b7\u30b9\u30c6\u30e0\u5185\u306e\u7dcf\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u793a\u3057\u3001\u5185\u90e8\u30a8\u30cd\u30eb\u30ae\u30fc (U) \u306b\u5727\u529b (P) \u3068\u4f53\u7a4d (V) \u306e\u7a4d\u3092\u52a0\u3048\u305f\u3082\u306e\u3067\u3059:<br \/>\n        <br \/> H = U + PV\n    <\/li>\n<li><b>\u30a8\u30f3\u30c8\u30ed\u30d4\u30fc (S)<\/b>: \u30a8\u30f3\u30c8\u30ed\u30d4\u30fc\u306f\u3001\u30b7\u30b9\u30c6\u30e0\u306e\u4e71\u96d1\u3055\u3084\u4e0d\u898f\u5247\u3055\u3092\u793a\u3059\u6307\u6a19\u3067\u3059\u3002\n    <\/li>\n<\/ul>\n<h2>\u30cd\u30eb\u30f3\u30b9\u30c8\u65b9\u7a0b\u5f0f<\/h2>\n<p>\n\u30cd\u30eb\u30f3\u30b9\u30c8\u65b9\u7a0b\u5f0f\u306f\u3001\u96fb\u6c60\u306e\u96fb\u4f4d\u304c\u6fc3\u5ea6\u306b\u3069\u306e\u3088\u3046\u306b\u4f9d\u5b58\u3059\u308b\u304b\u3092\u8a18\u8ff0\u3057\u307e\u3059\u3002\u6a19\u6e96\u96fb\u6975\u96fb\u4f4d \\(E^\\circ\\) \u3068\u53cd\u5fdc\u306e\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316 (\\( \\Delta G^\\circ \\)) \u306e\u95a2\u4fc2\u306f\u6b21\u306e\u5f0f\u3067\u8868\u3055\u308c\u307e\u3059:\n<\/p>\n<p>\n\\( \\Delta G^\\circ = -nFE^\\circ \\)\n<\/p>\n<p>\n\u3053\u3053\u3067\u3001\\( n \\) \u306f\u96fb\u5b50\u306e\u30e2\u30eb\u6570\u3001\\( F \\) \u306f\u30d5\u30a1\u30e9\u30c7\u30fc\u5b9a\u6570\uff08\u7d04 96485 C\/mol\uff09\u3067\u3059\u3002\u30cd\u30eb\u30f3\u30b9\u30c8\u65b9\u7a0b\u5f0f\u306f\u6b21\u306e\u3088\u3046\u306b\u8868\u3055\u308c\u307e\u3059:\n<\/p>\n<p>\n\\[ E = E^\\circ &#8211; \\frac{RT}{nF} \\ln Q \\]\n<\/p>\n<p>\n\u3053\u3053\u3067\u3001\\( R \\) \u306f\u6c17\u4f53\u5b9a\u6570\uff08\u7d04 8.314 J\/(mol\u00b7K)\uff09\u3001\\( T \\) \u306f\u7d76\u5bfe\u6e29\u5ea6\u3001\\( Q \\) \u306f\u53cd\u5fdc\u5546\u3067\u3059\u3002\n<\/p>\n<h2>\u96fb\u6c60\u306e\u52b9\u7387<\/h2>\n<p>\n\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306b\u304a\u3051\u308b\u52b9\u7387\u306f\u3001\u5927\u307e\u304b\u306b\u8a00\u3048\u3070\u3001\u6295\u5165\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u5bfe\u3057\u3066\u5f97\u3089\u308c\u308b\u6709\u7528\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5272\u5408\u3092\u793a\u3057\u307e\u3059\u3002\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u5316 (\\( \\Delta G \\)) \u3068\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u5909\u5316 (\\( \\Delta H \\)) \u3092\u4f7f\u3046\u3053\u3068\u3067\u3001\u305d\u306e\u52b9\u7387\u306f\u6b21\u306e\u3088\u3046\u306b\u5b9a\u7fa9\u3055\u308c\u307e\u3059:\n<\/p>\n<p>\n\\[ \\text{\u52b9\u7387} = \\frac{\\Delta G}{\\Delta H} \\]\n<\/p>\n<p>\n\u7406\u60f3\u7684\u306a\u5834\u5408\u3001\u5168\u3066\u306e\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u304c\u6709\u7528\u306a\u96fb\u6c17\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u5909\u63db\u3055\u308c\u307e\u3059\u304c\u3001\u5b9f\u969b\u306b\u306f\u30a8\u30cd\u30eb\u30ae\u30fc\u640d\u5931\u304c\u907f\u3051\u3089\u308c\u306a\u3044\u305f\u3081\u3001\u52b9\u7387\u306f\u5e38\u306b 100% \u672a\u6e80\u3067\u3059\u3002\n<\/p>\n<h2>\u307e\u3068\u3081<\/h2>\n<p>\n\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\u306f\u3001\u5316\u5b66\u30a8\u30cd\u30eb\u30ae\u30fc\u3068\u96fb\u6c17\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u5909\u63db\u306b\u95a2\u3059\u308b\u57fa\u790e\u7684\u306a\u77e5\u8b58\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002\u30cd\u30eb\u30f3\u30b9\u30c8\u65b9\u7a0b\u5f0f\u3084\u30ae\u30d6\u30ba\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u6982\u5ff5\u3092\u7406\u89e3\u3059\u308b\u3053\u3068\u3067\u3001\u96fb\u6c60\u3084\u96fb\u89e3\u30bb\u30eb\u306a\u3069\u306e\u96fb\u6c17\u5316\u5b66\u7684\u30b7\u30b9\u30c6\u30e0\u306e\u52b9\u7387\u3068\u52d5\u4f5c\u3092\u3088\u308a\u6df1\u304f\u7406\u89e3\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3067\u3057\u3087\u3046\u3002\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\u306f\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\u306e\u52b9\u7387\u5316\u3084\u65b0\u30a8\u30cd\u30eb\u30ae\u30fc\u6280\u8853\u306e\u958b\u767a\u306b\u304a\u3044\u3066\u91cd\u8981\u306a\u5f79\u5272\u3092\u679c\u305f\u3057\u307e\u3059\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u96fb\u6c17\u5316\u5b66\u53cd\u5fdc\u306e\u71b1\u529b\u5b66\u306b\u3064\u3044\u3066\u57fa\u672c\u6982\u5ff5\u304b\u3089\u30cd\u30eb\u30f3\u30b9\u30c8\u65b9\u7a0b\u5f0f\u3001\u96fb\u6c60\u306e\u52b9\u7387\u307e\u3067\u3092\u521d\u5fc3\u8005\u5411\u3051\u306b\u89e3\u8aac\u3002\u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\u306e\u7406\u89e3\u306b\u6700\u9069\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[125],"tags":[],"yoast_head":"<!-- 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