{"id":357870,"date":"2024-06-22T09:27:22","date_gmt":"2024-06-22T08:27:22","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/%ea%b3%a0%eb%b6%84%ec%9e%90-%ec%9a%a9%ec%95%a1%ec%9d%98-%ed%86%b5%ea%b3%84-%ec%97%b4%ec%97%ad%ed%95%99\/"},"modified":"2024-06-22T09:27:22","modified_gmt":"2024-06-22T08:27:22","slug":"%ea%b3%a0%eb%b6%84%ec%9e%90-%ec%9a%a9%ec%95%a1%ec%9d%98-%ed%86%b5%ea%b3%84-%ec%97%b4%ec%97%ad%ed%95%99","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/ko\/%ea%b3%a0%eb%b6%84%ec%9e%90-%ec%9a%a9%ec%95%a1%ec%9d%98-%ed%86%b5%ea%b3%84-%ec%97%b4%ec%97%ad%ed%95%99\/","title":{"rendered":"\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559"},"content":{"rendered":"<p class=\"sidekick\">\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\uc5d0 \ub300\ud574 \uc124\uba85\ud558\uace0, \uace0\ubd84\uc790 \uc2dc\uc2a4\ud15c\uc758 \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0, \ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4 \uc774\ub860, \uc6a9\ub9e4-\uace0\ubd84\uc790 \uc0c1\ud638\uc791\uc6a9 \ub4f1\uc744 \ub2e4\ub8f9\ub2c8\ub2e4.<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/06\/\uace0\ubd84\uc790_\uc6a9\uc561\uc758_\ud1b5\uacc4_\uc5f4\uc5ed\ud559.png\" alt=\"\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559<\/h2>\n<p>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\uc740 \uace0\ubd84\uc790 \ubb3c\uc9c8\uc758 \uac70\ub3d9\uc744 \uc774\ud574\ud558\ub294 \ub370 \uc911\uc694\ud55c \ud559\ubb38 \ubd84\uc57c\uc785\ub2c8\ub2e4. \uace0\ubd84\uc790(PM: Polymer) \uc6a9\uc561\uc740 \uc77c\uc0c1\uc0dd\ud65c\uc5d0\uc11c \ub110\ub9ac \uc0ac\uc6a9\ub418\uba70, \ud2b9\ud788 \ud50c\ub77c\uc2a4\ud2f1, \uace0\ubb34, \uc12c\uc720 \ubc0f \uc0dd\uccb4 \ubb3c\uc9c8\uc5d0\uc11c \ud070 \uc5ed\ud560\uc744 \ud569\ub2c8\ub2e4. \uc774 \uae00\uc5d0\uc11c\ub294 \uace0\ubd84\uc790 \uc6a9\uc561\uc758 \uae30\ubcf8 \uac1c\ub150\uacfc \uc5f4\uc5ed\ud559\uc801 \uc6d0\ub9ac\ub97c \uc54c\uc544\ubcf4\uaca0\uc2b5\ub2c8\ub2e4.<\/p>\n<h2>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \uad6c\uc131<\/h2>\n<p>\uace0\ubd84\uc790 \uc6a9\uc561\uc740 \uc8fc\ub85c \ub450 \uac00\uc9c0 \uc131\ubd84\uc73c\ub85c \uad6c\uc131\ub429\ub2c8\ub2e4: \uace0\ubd84\uc790 \uc0ac\uc2ac\uacfc \uc6a9\ub9e4\uc785\ub2c8\ub2e4. \uc6a9\ub9e4\ub294 \uace0\ubd84\uc790 \uc0ac\uc2ac\uc744 \ub179\uc5ec\uc8fc\ub294 \uc5ed\ud560\uc744 \ud558\uba70, \uace0\ubd84\uc790 \uc0ac\uc2ac\uc740 \ub2e4\uc591\ud55c \ub2e8\ub7c9\uccb4(monomer)\uac00 \uae34 \uc0ac\uc2ac \ubaa8\uc591\uc73c\ub85c \uc5f0\uacb0\ub41c \uad6c\uc870\ub97c \uac00\uc9d1\ub2c8\ub2e4.<\/p>\n<h2>\ud1b5\uacc4 \uc5f4\uc5ed\ud559 \uac1c\uc694<\/h2>\n<p>\ud1b5\uacc4 \uc5f4\uc5ed\ud559(statistical thermodynamics)\uc740 \ub2e4\uc218\uc758 \uc785\uc790\ub85c \uc774\ub904\uc9c4 \uc2dc\uc2a4\ud15c\uc758 \uac70\ub3d9\uc744 \ubd84\uc11d\ud558\ub294 \ud559\ubb38\uc785\ub2c8\ub2e4. \uc774 \ubc29\ubc95\ub860\uc744 \ud1b5\ud574 \uace0\ubd84\uc790 \uc0ac\uc2ac\uacfc \uc6a9\ub9e4 \uac04\uc758 \uc0c1\ud638\uc791\uc6a9, \uc790\uc720 \uc5d0\ub108\uc9c0, \uc5d4\ud2b8\ub85c\ud53c \ubc0f \uc5d4\ud0c8\ud53c\ub97c \ubd84\uc11d\ud560 \uc218 \uc788\uc2b5\ub2c8\ub2e4.<\/p>\n<h2>\ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0<\/h2>\n<p>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \uc5f4\uc5ed\ud559\uc801 \ud2b9\uc131\uc744 \uc774\ud574\ud558\uae30 \uc704\ud574 \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0(mixing free energy)\ub97c \ubd84\uc11d\ud574\uc57c \ud569\ub2c8\ub2e4. \uc774\ub294 \uc544\ub798\uc640 \uac19\uc740 \uc218\uc2dd\uc73c\ub85c \ud45c\ud604\ud560 \uc218 \uc788\uc2b5\ub2c8\ub2e4:<\/p>\n<p>\\( \\Delta G_{mix} = \\Delta H_{mix} &#8211; T \\Delta S_{mix} \\)<\/p>\n<ul>\n<li>\\( \\Delta G_{mix} \\): \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0 \ubcc0\ud654<\/li>\n<li>\\( \\Delta H_{mix} \\): \ud63c\ud569 \uc5d4\ud0c8\ud53c \ubcc0\ud654<\/li>\n<li>\\( T \\): \uc808\ub300 \uc628\ub3c4<\/li>\n<li>\\( \\Delta S_{mix} \\): \ud63c\ud569 \uc5d4\ud2b8\ub85c\ud53c \ubcc0\ud654<\/li>\n<\/ul>\n<h2>\ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4 \uc774\ub860<\/h2>\n<p>\ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4(Flory-Huggins) \uc774\ub860\uc740 \uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0\ub97c \uc608\uce21\ud558\ub294 \ub370 \uc720\uc6a9\ud55c \ubaa8\ub378\uc785\ub2c8\ub2e4. \uc774 \ubaa8\ub378\uc740 \uace0\ubd84\uc790\uc640 \uc6a9\ub9e4 \ubd84\uc790\uc758 \uc704\uce58 \ubcc0\ud654\ub97c \ud1b5\uacc4\uc801\uc73c\ub85c \ubd84\uc11d\ud558\uc5ec \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0\ub97c \uacc4\uc0b0\ud569\ub2c8\ub2e4. \ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4 \ubc29\uc815\uc2dd\uc740 \ub2e4\uc74c\uacfc \uac19\uc2b5\ub2c8\ub2e4:<\/p>\n<p>\\( \\Delta G_{mix} = RT (\\frac{\\phi P}{N} \\ln \\phi P + \\phi S \\ln \\phi S + \\chi \\phi P \\phi S) \\)<\/p>\n<ul>\n<li>\\( R \\): \uae30\uccb4 \uc0c1\uc218<\/li>\n<li>\\( T \\): \uc628\ub3c4<\/li>\n<li>\\( \\phi P \\): \uace0\ubd84\uc790 \uccb4\uc801\ubd84\uc728<\/li>\n<li>\\( \\phi S \\): \uc6a9\ub9e4 \uccb4\uc801\ubd84\uc728<\/li>\n<li>\\( N \\): \uace0\ubd84\uc790 \uc0ac\uc2ac\uc758 \ub2e8\uc704\uccb4 \uc218<\/li>\n<li>\\( \\chi \\): \uc6a9\ub9e4-\uace0\ubd84\uc790 \uc0c1\ud638\uc791\uc6a9 \ub9e4\uac1c\ubcc0\uc218<\/li>\n<\/ul>\n<h2>\uc6a9\ub9e4-\uace0\ubd84\uc790 \uc0c1\ud638\uc791\uc6a9<\/h2>\n<p>\uc6a9\ub9e4\uc640 \uace0\ubd84\uc790 \uc0ac\uc2ac \uc0ac\uc774\uc758 \uc0c1\ud638\uc791\uc6a9\uc740 \uc6a9\uc561\uc758 \uac70\ub3d9\uc5d0 \ud070 \uc601\ud5a5\uc744 \ubbf8\uce69\ub2c8\ub2e4. \\( \\chi \\) \uc0c1\ud638\uc791\uc6a9 \ub9e4\uac1c\ubcc0\uc218\uac00 \uc774\ub7ec\ud55c \uc0c1\ud638\uc791\uc6a9\uc758 \uac15\ub3c4\ub97c \ub098\ud0c0\ub0c5\ub2c8\ub2e4. \\( \\chi \\) \uac12\uc774 \uc791\uc744\uc218\ub85d \uc6a9\ub9e4\uc640 \uace0\ubd84\uc790\uac00 \uc798 \uc11e\uc774\ub294 \ubc18\uba74, \\( \\chi \\) \uac12\uc774 \ud074\uc218\ub85d \ubd84\ub9ac\uac00 \uc27d\uac8c \uc77c\uc5b4\ub0a9\ub2c8\ub2e4.<\/p>\n<h2>\uc751\uc6a9 \uc608\uc2dc<\/h2>\n<p>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\uc740 \ub2e4\uc591\ud55c \uc0b0\uc5c5\uc801 \uc751\uc6a9\uc774 \uc788\uc2b5\ub2c8\ub2e4:<\/p>\n<ol>\n<li>\ud50c\ub77c\uc2a4\ud2f1 \uc0dd\uc0b0: \uace0\ubd84\uc790 \uc0ac\uc2ac\uc758 \ubc30\ud569\uacfc \uc6a9\ub9e4 \uc120\ud0dd<\/li>\n<li>\ub098\ub178\uc18c\uc7ac: \ub098\ub178 \uc785\uc790\uc640 \uace0\ubd84\uc790 \ub9e4\ud2b8\ub9ad\uc2a4\uc758 \ud63c\ud569<\/li>\n<li>\uc758\ub8cc: \uc0dd\uccb4\uc801\ud569\uc131 \uace0\ubd84\uc790\uc758 \uc6a9\uc561 \ud2b9\uc131 \ubd84\uc11d<\/li>\n<\/ol>\n<h2>\uacb0\ub860<\/h2>\n<p>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\uc740 \uace0\ubd84\uc790 \uc2dc\uc2a4\ud15c\uc758 \ud2b9\uc131\uc744 \uc774\ud574\ud558\uace0 \ub2e4\uc591\ud55c \uc751\uc6a9 \ubd84\uc57c\uc5d0 \uc801\uc6a9\ud560 \uc218 \uc788\ub294 \uc911\uc694\ud55c \ub3c4\uad6c\uc785\ub2c8\ub2e4. \uc774 \uae00\uc5d0\uc11c\ub294 \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0, \ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4 \uc774\ub860 \ubc0f \uc6a9\ub9e4-\uace0\ubd84\uc790 \uc0c1\ud638\uc791\uc6a9\uc744 \uc911\uc2ec\uc73c\ub85c \uc0b4\ud3b4\ubcf4\uc558\uc2b5\ub2c8\ub2e4. \uc774\ub7ec\ud55c \uc774\ub860\uc801 \ud1a0\ub300\ub97c \ubc14\ud0d5\uc73c\ub85c, \ub2e4\uc591\ud55c \uc2e4\uc9c8\uc801 \uc751\uc6a9\uc5d0\uc11c \uace0\ubd84\uc790 \ubb3c\uc9c8\uc758 \ud2b9\uc131\uc744 \uc870\uc808\ud560 \uc218 \uc788\uc2b5\ub2c8\ub2e4.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\uc5d0 \ub300\ud574 \uc124\uba85\ud558\uace0, \uace0\ubd84\uc790 \uc2dc\uc2a4\ud15c\uc758 \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0, \ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4 \uc774\ub860, \uc6a9\ub9e4-\uace0\ubd84\uc790 \uc0c1\ud638\uc791\uc6a9 \ub4f1\uc744 \ub2e4\ub8f9\ub2c8\ub2e4.<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[124],"tags":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v15.4 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559<\/title>\n<meta name=\"description\" content=\"\uace0\ubd84\uc790 \uc6a9\uc561\uc758 \ud1b5\uacc4 \uc5f4\uc5ed\ud559\uc5d0 \ub300\ud574 \uc124\uba85\ud558\uace0, \uace0\ubd84\uc790 \uc2dc\uc2a4\ud15c\uc758 \ud63c\ud569 \uc790\uc720 \uc5d0\ub108\uc9c0, \ud50c\ub85c\ub9ac-\ud558\uae34\uc2a4 \uc774\ub860, \uc6a9\ub9e4-\uace0\ubd84\uc790 \uc0c1\ud638\uc791\uc6a9 \ub4f1\uc744 \ub2e4\ub8f9\ub2c8\ub2e4.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" 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