{"id":720587,"date":"2024-11-29T19:05:08","date_gmt":"2024-11-29T18:05:08","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/?p=720587"},"modified":"2024-11-29T19:05:08","modified_gmt":"2024-11-29T18:05:08","slug":"%e7%83%ad%e6%bf%80%e5%bb%b6%e8%bf%9f%e8%8d%a7%e5%85%89%e7%81%af%e7%9a%84%e5%b7%a5%e4%bd%9c%e5%8e%9f%e7%90%86","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%83%ad%e6%bf%80%e5%bb%b6%e8%bf%9f%e8%8d%a7%e5%85%89%e7%81%af%e7%9a%84%e5%b7%a5%e4%bd%9c%e5%8e%9f%e7%90%86\/","title":{"rendered":"\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406"},"content":{"rendered":"<p class=\"sidekick\">\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406\uff1a\u901a\u8fc7\u70ed\u6fc0\u53d1\u8fc7\u7a0b\u5ef6\u8fdf\u8367\u5149\u53d1\u5c04\uff0c\u63d0\u9ad8\u5149\u6548\uff0c\u8282\u80fd\u73af\u4fdd\uff0c\u6df1\u5165\u89e3\u6790\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u4f18\u52bf\u4e0e\u6311\u6218\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/07\/\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406.png\" alt=\"\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406<\/h2>\n<p>\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\uff08Thermally Activated Delayed Fluorescence, TADF\uff09\u662f\u4e00\u79cd\u65b0\u578b\u8367\u5149\u706f\uff0c\u5176\u6838\u5fc3\u539f\u7406\u4f9d\u8d56\u4e8e\u70ed\u6fc0\u53d1\u548c\u5ef6\u8fdf\u8367\u5149\u8fd9\u4e24\u4e2a\u57fa\u672c\u7269\u7406\u73b0\u8c61\u3002\u4e0e\u4f20\u7edf\u8367\u5149\u706f\u76f8\u6bd4\uff0cTADF\u706f\u5728\u6548\u7387\u548c\u73af\u4fdd\u65b9\u9762\u5177\u6709\u663e\u8457\u4f18\u52bf\u3002\u672c\u6587\u5c06\u4ecb\u7ecdTADF\u706f\u7684\u5de5\u4f5c\u539f\u7406\u4ee5\u53ca\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u4f18\u52bf\u3002<\/p>\n<h2>\u57fa\u672c\u539f\u7406<\/h2>\n<p>TADF\u706f\u7684\u5de5\u4f5c\u539f\u7406\u4e3b\u8981\u5305\u62ec\u4ee5\u4e0b\u51e0\u4e2a\u6b65\u9aa4\uff1a<\/p>\n<ol>\n<li> <b>\u7535\u6fc0\u53d1:<\/b> \u5f53\u706f\u88ab\u901a\u7535\u540e\uff0c\u5143\u4ef6\u5185\u7684\u7535\u5b50\u88ab\u6fc0\u53d1\u5230\u8f83\u9ad8\u7684\u80fd\u91cf\u72b6\u6001\uff0c\u5373\u6fc0\u53d1\u6001\uff08Excited State\uff09\u3002\u8fd9\u4e00\u6b65\u548c\u6240\u6709\u8367\u5149\u6750\u6599\u7684\u5de5\u4f5c\u539f\u7406\u7c7b\u4f3c\u3002<\/li>\n<li> <b>\u4e09\u91cd\u6001\u548c\u5355\u91cd\u6001\u7684\u533a\u522b:<\/b> \u5728\u5927\u591a\u6570\u8367\u5149\u6750\u6599\u4e2d\uff0c\u7535\u5b50\u4ece\u6fc0\u53d1\u6001\u56de\u5230\u57fa\u6001\uff08Ground State\uff09\u7684\u8fc7\u7a0b\u4e2d\u4f1a\u4ea7\u751f\u8367\u5149\u3002\u7136\u800c\u5728TADF\u6750\u6599\u4e2d\uff0c\u7535\u5b50\u53ef\u4ee5\u8fdb\u5165\u4e00\u79cd\u88ab\u79f0\u4e3a\u4e09\u91cd\u6001\uff08Triplet State\uff09\u548c\u5355\u91cd\u6001\uff08Singlet State\uff09\u7684\u80fd\u6001\u3002<\/li>\n<li> <b>\u70ed\u6fc0\u53d1\u534f\u52a9:<\/b> \u4e09\u91cd\u6001\u548c\u5355\u91cd\u6001\u4e4b\u95f4\u5b58\u5728\u4e00\u4e2a\u8f83\u5c0f\u7684\u80fd\u91cf\u5dee\uff0c\u8fd9\u4e2a\u5dee\u8ddd\u5141\u8bb8\u4e09\u91cd\u6001\u5728\u4e00\u5b9a\u6e29\u5ea6\u4e0b\u901a\u8fc7\u70ed\u6fc0\u53d1\u8f6c\u53d8\u4e3a\u5355\u91cd\u6001\u3002\u8fd9\u79cd\u8fc7\u7a0b\u79f0\u4e3a\u53cd\u65af\u6258\u514b\u65af\u4f4d\u79fb\u3002<\/li>\n<li> <b>\u5ef6\u8fdf\u8367\u5149:<\/b> \u5f53\u7535\u5b50\u4ece\u4e09\u91cd\u6001\u501f\u52a9\u70ed\u6fc0\u53d1\u56de\u5230\u5355\u91cd\u6001\u540e\uff0c\u4f1a\u91cd\u65b0\u56de\u5230\u57fa\u6001\u5e76\u4e14\u53d1\u51fa\u8367\u5149\u3002\u8fd9\u5c31\u662f\u6240\u8c13\u7684\u5ef6\u8fdf\u8367\u5149\u3002<\/li>\n<\/ol>\n<p>\u603b\u7684\u6765\u8bf4\uff0cTADF\u706f\u901a\u8fc7\u7535\u6fc0\u53d1\u548c\u70ed\u6fc0\u53d1\u5171\u540c\u4f5c\u7528\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684\u5149\u5b50\u53d1\u5c04\u3002<\/p>\n<h2>\u4f18\u52bf<\/h2>\n<p>TADF\u706f\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u5177\u6709\u591a\u4e2a\u4f18\u52bf\uff1a<\/p>\n<ol>\n<li> <b>\u9ad8\u6548\u7387:<\/b> \u7531\u4e8eTADF\u91c7\u7528\u4e86\u70ed\u6fc0\u53d1\u673a\u5236\uff0c\u5b83\u80fd\u591f\u6709\u6548\u5229\u7528\u4e09\u91cd\u6001\uff0c\u5b9e\u73b0\u51e0\u4e4e100%\u7684\u5185\u91cf\u5b50\u6548\u7387\uff08Internal Quantum Efficiency, IQE\uff09\u3002<\/li>\n<li> <b>\u73af\u4fdd:<\/b> \u4f20\u7edf\u8367\u5149\u706f\u5e38\u5e38\u4f7f\u7528\u542b\u6c5e\u7b49\u6709\u5bb3\u6750\u6599\uff0c\u800cTADF\u706f\u53ef\u4ee5\u4f7f\u7528\u65e0\u6bd2\u6750\u6599\uff0c\u51cf\u5c11\u73af\u5883\u6c61\u67d3\u3002<\/li>\n<li> <b>\u957f\u5bff\u547d:<\/b> TADF\u706f\u7684\u6750\u6599\u7a33\u5b9a\u6027\u8f83\u9ad8\uff0c\u4f7f\u7528\u5bff\u547d\u6bd4\u4f20\u7edf\u8367\u5149\u706f\u66f4\u957f\u3002<\/li>\n<li> <b>\u5e7f\u6cdb\u5e94\u7528:<\/b> TADF\u6280\u672f\u4e0d\u4ec5\u53ef\u7528\u4e8e\u666e\u901a\u7167\u660e\uff0c\u8fd8\u53ef\u4ee5\u5e94\u7528\u4e8e\u663e\u793a\u6280\u672f\u3001\u5149\u5b66\u4f20\u611f\u5668\u7b49\u9ad8\u79d1\u6280\u9886\u57df\u3002<\/li>\n<\/ol>\n<p>\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u56e0\u4e3a\u5176\u72ec\u7279\u7684\u5de5\u4f5c\u539f\u7406\u548c\u663e\u8457\u7684\u4f18\u52bf\uff0c\u6b63\u5728\u9010\u6b65\u53d6\u4ee3\u4f20\u7edf\u7684\u8367\u5149\u548cLED\u6280\u672f\uff0c\u6210\u4e3a\u672a\u6765\u7167\u660e\u548c\u663e\u793a\u9886\u57df\u7684\u4e3b\u529b\u519b\u3002<\/p>\n<h2>\u7ed3\u8bba<\/h2>\n<p>\u7406\u89e3\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406\u6709\u52a9\u4e8e\u6211\u4eec\u66f4\u597d\u5730\u5229\u7528\u548c\u63a8\u5e7f\u8fd9\u4e00\u9ad8\u6548\u73af\u4fdd\u7684\u7167\u660e\u6280\u672f\u3002\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0cTADF\u706f\u5c06\u5728\u66f4\u591a\u9886\u57df\u5185\u5f97\u5230\u5e7f\u6cdb\u5e94\u7528\uff0c\u4e3a\u4eba\u7c7b\u751f\u6d3b\u5e26\u6765\u66f4\u591a\u4fbf\u5229\u548c\u7eff\u8272\u80fd\u6e90\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u70ed\u6fc0\u5ef6\u8fdf\u8367\u5149\u706f\u7684\u5de5\u4f5c\u539f\u7406\uff1a\u901a\u8fc7\u70ed\u6fc0\u53d1\u8fc7\u7a0b\u5ef6\u8fdf\u8367\u5149\u53d1\u5c04\uff0c\u63d0\u9ad8\u5149\u6548\uff0c\u8282\u80fd\u73af\u4fdd\uff0c\u6df1\u5165\u89e3\u6790\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u4f18\u52bf\u4e0e\u6311\u6218\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[134],"tags":[],"yoast_head":"<!-- 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