{"id":740836,"date":"2024-10-10T19:29:21","date_gmt":"2024-10-10T18:29:21","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/?p=740836"},"modified":"2024-10-10T19:29:21","modified_gmt":"2024-10-10T18:29:21","slug":"%e9%ab%98%e5%88%86%e5%ad%90%e6%ba%b6%e6%b6%b2%e7%9a%84%e7%bb%9f%e8%ae%a1%e7%83%ad%e5%8a%9b%e5%ad%a6","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/zh-hans\/%e9%ab%98%e5%88%86%e5%ad%90%e6%ba%b6%e6%b6%b2%e7%9a%84%e7%bb%9f%e8%ae%a1%e7%83%ad%e5%8a%9b%e5%ad%a6\/","title":{"rendered":"\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66"},"content":{"rendered":"<p class=\"sidekick\">\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66\u6587\u7ae0\u4ecb\u7ecd\u4e86\u9ad8\u5206\u5b50\u6eb6\u6db2\u884c\u4e3a\u7684\u57fa\u672c\u539f\u7406\uff0c\u901a\u8fc7\u7edf\u8ba1\u65b9\u6cd5\u5206\u6790\u5176\u70ed\u529b\u5b66\u7279\u6027\uff0c\u5e2e\u52a9\u8bfb\u8005\u7406\u89e3\u6b64\u91cd\u8981\u5de5\u7a0b\u5206\u652f\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/07\/\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66.png\" alt=\"\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66<\/h2>\n<p>\u9ad8\u5206\u5b50\u6eb6\u6db2\u662f\u7531\u9ad8\u5206\u5b50\u548c\u6eb6\u5242\u7ec4\u6210\u7684\u6df7\u5408\u7269\u3002\u7edf\u8ba1\u70ed\u529b\u5b66\u5728\u7814\u7a76\u9ad8\u5206\u5b50\u6eb6\u6db2\u4e2d\u5206\u5b50\u7684\u884c\u4e3a\u65f6\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u901a\u8fc7\u5e94\u7528\u7edf\u8ba1\u529b\u5b66\uff0c\u6211\u4eec\u53ef\u4ee5\u7406\u89e3\u548c\u9884\u6d4b\u8fd9\u4e9b\u6df7\u5408\u7269\u7684\u70ed\u529b\u5b66\u6027\u8d28\u3002<\/p>\n<h2>\u57fa\u672c\u6982\u5ff5<\/h2>\n<p>\u5728\u8ba8\u8bba\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66\u65f6\uff0c\u6709\u51e0\u4e2a\u5173\u952e\u6982\u5ff5\u503c\u5f97\u4e86\u89e3\uff1a<\/p>\n<p><u1><\/p>\n<li><b>\u9ad8\u5206\u5b50\uff1a<\/b>\u7531\u5927\u91cf\u91cd\u590d\u5355\u5143\uff08\u5355\u4f53\uff09\u901a\u8fc7\u5316\u5b66\u952e\u8fde\u63a5\u800c\u6210\u7684\u957f\u94fe\u5206\u5b50\u3002<\/li>\n<li><b>\u6eb6\u5242\uff1a<\/b>\u7528\u6765\u6eb6\u89e3\u5176\u4ed6\u7269\u8d28\u7684\u6db2\u4f53\uff0c\u4f8b\u5982\u6c34\u6216\u4e59\u9187\u3002<\/li>\n<li><b>\u6df7\u5408\u81ea\u7531\u80fd\uff1a<\/b>\u63cf\u8ff0\u4e86\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u6df7\u5408\u8fc7\u7a0b\u4e2d\u7684\u81ea\u7531\u80fd\u53d8\u5316\u3002<\/li>\n<li><b>\u71b5\uff1a<\/b>\u4e00\u4e2a\u7cfb\u7edf\u7684\u65e0\u5e8f\u5ea6\u91cf\uff0c\u662f\u7cfb\u7edf\u4e2d\u53ef\u80fd\u5fae\u89c2\u72b6\u6001\u7684\u6570\u76ee\u7684\u5bf9\u6570\u3002<\/li>\n<li><b>\u9759\u7535\u52bf\u80fd\uff1a<\/b>\u5e26\u7535\u7c92\u5b50\u4e4b\u95f4\u7684\u4f5c\u7528\u529b\u3002<\/li>\n<p><\/u1><\/p>\n<h2>\u5f17\u6d1b\u91cc-\u54c8\u91d1\u65af\u7406\u8bba<\/h2>\n<p>\u5f17\u6d1b\u91cc-\u54c8\u91d1\u65af(Flory-Huggins)\u7406\u8bba\u662f\u7814\u7a76\u9ad8\u5206\u5b50\u6eb6\u6db2\u70ed\u529b\u5b66\u884c\u4e3a\u7684\u57fa\u672c\u7406\u8bba\u3002\u5b83\u63d0\u4f9b\u4e86\u5b9a\u91cf\u63cf\u8ff0\u6df7\u5408\u81ea\u7531\u80fd\u7684\u65b9\u6cd5\u3002\u6839\u636e\u5f17\u6d1b\u91cc-\u54c8\u91d1\u65af\u7406\u8bba\uff0c\u6df7\u5408\u81ea\u7531\u80fd(\\( \\Delta G \\))\u53ef\u4ee5\u8868\u793a\u4e3a\uff1a<\/p>\n<p>\\[<br \/>\n\\Delta G = RT \\left( \\frac{\\phi_1}{N_1} \\ln \\phi_1 + \\frac{\\phi_2}{N_2} \\ln \\phi_2 + \\chi \\phi_1 \\phi_2 \\right)<br \/>\n\\]\n<p>\u5176\u4e2d\uff1a<\/p>\n<p><o1><\/p>\n<li>\\( R \\) \u662f\u6c14\u4f53\u5e38\u6570<\/li>\n<li>\\( T \\) \u662f\u7edd\u5bf9\u6e29\u5ea6<\/li>\n<li>\\( \\phi_1 \\) \u548c \\( \\phi_2 \\) \u5206\u522b\u662f\u6eb6\u5242\u548c\u9ad8\u5206\u5b50\u7684\u4f53\u79ef\u5206\u6570<\/li>\n<li>\\( N_1 \\) \u548c \\( N_2 \\) \u5206\u522b\u662f\u6eb6\u5242\u548c\u9ad8\u5206\u5b50\u7684\u805a\u5408\u5ea6<\/li>\n<li>\\( \\chi \\) \u662f\u5f17\u6d1b\u91cc-\u54c8\u91d1\u65af\u76f8\u4e92\u4f5c\u7528\u53c2\u6570<\/li>\n<p><\/o1><\/p>\n<p>\u8be5\u516c\u5f0f\u4e2d\uff0c\u7b2c\u4e00\u9879\u548c\u7b2c\u4e8c\u9879\u4ee3\u8868\u6df7\u5408\u71b5\uff0c\u7b2c\u4e09\u9879\u8868\u793a\u6df7\u5408\u7113\u3002<\/p>\n<h2>\u76f8\u4e92\u4f5c\u7528\u53c2\u6570 ( \\(\\chi\\) )<\/h2>\n<p>\u76f8\u4e92\u4f5c\u7528\u53c2\u6570 \\( \\chi \\) \u8868\u793a\u9ad8\u5206\u5b50\u6eb6\u6db2\u4e2d\u9ad8\u5206\u5b50\u4e0e\u6eb6\u5242\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u5f3a\u5ea6\u3002\u5b83\u7531\u4ee5\u4e0b\u516c\u5f0f\u8ba1\u7b97\uff1a<\/p>\n<p>\\[<br \/>\n\\chi = \\frac{z \\Delta \\epsilon}{RT}<br \/>\n\\]\n<p>\u5176\u4e2d\uff1a<\/p>\n<p><o1><\/p>\n<li>\\( z \\) \u662f\u6eb6\u6db2\u4e2d\u7684\u6709\u6548\u914d\u4f4d\u6570<\/li>\n<li>\\( \\Delta \\epsilon \\) \u662f\u9ad8\u5206\u5b50\u548c\u6eb6\u5242\u4e4b\u95f4\u7684\u6df7\u5408\u7113<\/li>\n<li>\\( R \\) \u662f\u6c14\u4f53\u5e38\u6570<\/li>\n<li>\\( T \\) \u662f\u7edd\u5bf9\u6e29\u5ea6<\/li>\n<p><\/o1><\/p>\n<h2>\u5e94\u7528\u53ca\u91cd\u8981\u6027<\/h2>\n<p>\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66\u5728\u6750\u6599\u79d1\u5b66\u3001\u5316\u5b66\u5de5\u7a0b\u548c\u751f\u7269\u5de5\u7a0b\u7b49\u9886\u57df\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u4f8b\u5982\uff0c\u5728\u9ad8\u5206\u5b50\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\uff0c\u7406\u89e3\u6eb6\u6db2\u884c\u4e3a\u5bf9\u5f00\u53d1\u65b0\u578b\u7535\u6c60\u548c\u5176\u4ed6\u80fd\u6e90\u5b58\u50a8\u8bbe\u5907\u81f3\u5173\u91cd\u8981\u3002\u6b64\u5916\uff0c\u8be5\u7406\u8bba\u4e5f\u5e94\u7528\u4e8e\u836f\u7269\u9012\u9001\u7cfb\u7edf\u548c\u98df\u54c1\u79d1\u5b66\u4e2d\u3002<\/p>\n<p>\u901a\u8fc7\u4e86\u89e3\u548c\u5e94\u7528\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66\uff0c\u79d1\u5b66\u5bb6\u548c\u5de5\u7a0b\u5e08\u53ef\u4ee5\u8bbe\u8ba1\u51fa\u66f4\u9ad8\u6548\u7684\u6750\u6599\u548c\u5de5\u827a\uff0c\u8fdb\u800c\u63a8\u52a8\u6280\u672f\u8fdb\u6b65\u548c\u4ea7\u4e1a\u53d1\u5c55\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u9ad8\u5206\u5b50\u6eb6\u6db2\u7684\u7edf\u8ba1\u70ed\u529b\u5b66\u6587\u7ae0\u4ecb\u7ecd\u4e86\u9ad8\u5206\u5b50\u6eb6\u6db2\u884c\u4e3a\u7684\u57fa\u672c\u539f\u7406\uff0c\u901a\u8fc7\u7edf\u8ba1\u65b9\u6cd5\u5206\u6790\u5176\u70ed\u529b\u5b66\u7279\u6027\uff0c\u5e2e\u52a9\u8bfb\u8005\u7406\u89e3\u6b64\u91cd\u8981\u5de5\u7a0b\u5206\u652f\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[134],"tags":[],"yoast_head":"<!-- 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