{"id":741833,"date":"2024-09-11T19:00:45","date_gmt":"2024-09-11T18:00:45","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/?p=741833"},"modified":"2024-09-11T19:00:45","modified_gmt":"2024-09-11T18:00:45","slug":"%e5%8f%af%e9%99%8d%e8%a7%a3%e6%9d%90%e6%96%99%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6%e7%89%b9%e6%80%a7","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/zh-hans\/%e5%8f%af%e9%99%8d%e8%a7%a3%e6%9d%90%e6%96%99%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6%e7%89%b9%e6%80%a7\/","title":{"rendered":"\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027"},"content":{"rendered":"

\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\uff1a\u4e86\u89e3\u8fd9\u4e9b\u73af\u4fdd\u6750\u6599\u5728\u4e0d\u540c\u6e29\u5ea6\u3001\u538b\u529b\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0\uff0c\u4ee5\u53ca\u5b83\u4eec\u5728\u73b0\u4ee3\u5de5\u7a0b\u4e2d\u7684\u5e94\u7528\u548c\u4f18\u52bf\u3002<\/p>\n

\"\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\"<\/p>\n

\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027<\/h2>\n

\u968f\u7740\u73af\u5883\u4fdd\u62a4\u610f\u8bc6\u7684\u589e\u5f3a\uff0c\u4eba\u4eec\u5bf9\u53ef\u964d\u89e3\u6750\u6599\u7684\u5173\u6ce8\u5ea6\u4e0d\u65ad\u4e0a\u5347\u3002\u53ef\u964d\u89e3\u6750\u6599\u56e0\u5176\u80fd\u591f\u5728\u81ea\u7136\u73af\u5883\u4e2d\u5206\u89e3\uff0c\u51cf\u5c11\u5bf9\u73af\u5883\u7684\u8d1f\u9762\u5f71\u54cd\uff0c\u6b63\u8fc5\u901f\u6210\u4e3a\u7814\u7a76\u548c\u5e94\u7528\u7684\u70ed\u70b9\u3002\u672c\u6587\u5c06\u63a2\u8ba8\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\uff0c\u4ee5\u5c55\u793a\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u70ed\u964d\u89e3\u673a\u5236<\/h2>\n

\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u964d\u89e3\u673a\u5236\u901a\u5e38\u5305\u62ec\u4e24\u90e8\u5206\uff1a\u70ed\u88c2\u89e3\uff08Pyrolysis\uff09\u548c\u70ed\u6c27\u5316\uff08Thermal Oxidation\uff09\u3002<\/p>\n

    \n
  1. \u70ed\u88c2\u89e3\uff1a\u6b64\u8fc7\u7a0b\u901a\u5e38\u53d1\u751f\u5728\u65e0\u6c27\u73af\u5883\u4e2d\uff0c\u901a\u8fc7\u52a0\u70ed\u4f7f\u5927\u5206\u5b50\u65ad\u88c2\u6210\u8f83\u5c0f\u7684\u5206\u5b50\u3002<\/li>\n
  2. \u70ed\u6c27\u5316\uff1a\u5728\u6709\u6c27\u73af\u5883\u4e0b\uff0c\u6750\u6599\u901a\u8fc7\u4e0e\u6c27\u6c14\u53cd\u5e94\u53d1\u751f\u6c27\u5316\u5206\u89e3\u3002<\/li>\n<\/ol>\n

    \u70ed\u529b\u5b66\u53c2\u6570<\/h2>\n

    \u7406\u89e3\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\uff0c\u4e3b\u8981\u4f9d\u8d56\u4e8e\u51e0\u4e2a\u5173\u952e\u53c2\u6570\uff1a<\/p>\n

      \n
    • \u7113 (H)<\/strong>\uff1a\u7113\u662f\u7cfb\u7edf\u70ed\u80fd\u7684\u603b\u548c\u3002\u5bf9\u4e8e\u53ef\u964d\u89e3\u6750\u6599\uff0c\u7113\u53d8\u5316\u4e0e\u6750\u6599\u7684\u70ed\u5206\u89e3\u80fd\u7d27\u5bc6\u76f8\u5173\u3002<\/li>\n
    • \u71b5 (S)<\/strong>\uff1a\u71b5\u8868\u793a\u7cfb\u7edf\u7684\u65e0\u5e8f\u7a0b\u5ea6\u3002\u5728\u6750\u6599\u964d\u89e3\u8fc7\u7a0b\u4e2d\uff0c\u71b5\u901a\u5e38\u4f1a\u589e\u52a0\u3002<\/li>\n
    • \u81ea\u7531\u80fd (G)<\/strong>\uff1a\u81ea\u7531\u80fd\u5b9a\u4e49\u4e3a\\( G = H – T \\cdot S \\)\u3002\u5bf9\u4e8e\u81ea\u53d1\u7684\u964d\u89e3\u8fc7\u7a0b\uff0c\u81ea\u7531\u80fd\u53d8\u5316 (\\(\\Delta G\\)) \u5fc5\u987b\u4e3a\u8d1f\u503c\u3002<\/li>\n<\/ul>\n

      \u70ed\u5206\u89e3\u52a8\u529b\u5b66<\/h2>\n

      \u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u5206\u89e3\u901a\u5e38\u53ef\u7528\u4e0b\u8ff0\u5dee\u5206\u65b9\u7a0b\u8868\u793a\uff1a<\/p>\n

      \\( \\frac{dX}{dt} = k(T) \\cdot f(X) \\)<\/p>\n

      \u5176\u4e2d\uff0c\\( X \\) \u4ee3\u8868\u53cd\u5e94\u8fdb\u5ea6\uff0c\\( k(T) \\) \u4e3a\u6e29\u5ea6\u51fd\u6570\uff0c\u4f53\u73b0\u4e86\u53cd\u5e94\u901f\u7387\u5e38\u6570\uff0c \\( f(X) \\) \u8868\u793a\u53cd\u5e94\u8fdb\u7a0b\u51fd\u6570\u3002\u5b9e\u9a8c\u4e0a\u5e38\u7528\u963f\u4f26\u5c3c\u4e4c\u65af\u65b9\u7a0b\u63cf\u8ff0\u53cd\u5e94\u901f\u7387\u5e38\u6570\uff1a<\/p>\n

      \\( k(T) = A \\cdot exp \\left( -\\frac{E_a}{R \\cdot T} \\right) \\)<\/p>\n

      \u5176\u4e2d\uff0c\\( A \\) \u662f\u9891\u7387\u56e0\u5b50\uff0c\\( E_a \\) \u662f\u6d3b\u5316\u80fd\uff0c\\( R \\) \u662f\u6c14\u4f53\u5e38\u6570\uff0c\\( T \\) \u662f\u6e29\u5ea6\u3002<\/p>\n

      \u5b9e\u9a8c\u6d4b\u5b9a\u65b9\u6cd5<\/h2>\n

      \u6d4b\u5b9a\u53ef\u964d\u89e3\u6750\u6599\u70ed\u529b\u5b66\u7279\u6027\u7684\u65b9\u6cd5\u5305\u62ec\u70ed\u91cd\u5206\u6790\uff08TGA\uff09\u548c\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09\uff1a<\/p>\n

        \n
      • \u70ed\u91cd\u5206\u6790\uff08TGA\uff09\uff1aTGA \u6d4b\u91cf\u6750\u6599\u8d28\u91cf\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u5173\u7cfb\uff0c\u5e2e\u52a9\u7406\u89e3\u6750\u6599\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5206\u89e3\u884c\u4e3a\u3002<\/li>\n
      • \u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09\uff1aDSC \u6d4b\u5b9a\u6750\u6599\u5728\u53d7\u70ed\u8fc7\u7a0b\u4e2d\u7684\u70ed\u6d41\u53d8\u5316\uff0c\u53ef\u7528\u6765\u8ba1\u7b97\u6750\u6599\u7684\u70ed\u7113\u548c\u71b5\u53d8\u3002<\/li>\n<\/ul>\n

        \u5b9e\u9645\u5e94\u7528<\/h2>\n

        \u7814\u7a76\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\u6709\u52a9\u4e8e\u4f18\u5316\u5176\u751f\u4ea7\u5de5\u827a\uff0c\u6539\u8fdb\u4ea7\u54c1\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u5728\u8bbe\u8ba1\u53ef\u964d\u89e3\u5851\u6599\u5305\u88c5\u6750\u6599\u65f6\uff0c\u901a\u8fc7\u4e86\u89e3\u5176\u70ed\u964d\u89e3\u7279\u6027\uff0c\u53ef\u4ee5\u9009\u62e9\u5408\u9002\u7684\u751f\u4ea7\u6e29\u5ea6\u548c\u964d\u89e3\u6761\u4ef6\uff0c\u4ee5\u8fbe\u6210\u6700\u4f73\u4f7f\u7528\u6548\u679c\u548c\u73af\u4fdd\u6027\u80fd\u3002<\/p>\n

        \u603b\u7ed3\u8d77\u6765\uff0c\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\u4e0d\u4ec5\u5f71\u54cd\u5176\u73af\u5883\u53cb\u597d\u6027\uff0c\u8fd8\u51b3\u5b9a\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u8868\u73b0\u3002\u901a\u8fc7\u6df1\u5165\u7814\u7a76\u8fd9\u4e9b\u7279\u6027\uff0c\u6211\u4eec\u53ef\u4ee5\u5b9e\u73b0\u66f4\u52a0\u7eff\u8272\u548c\u53ef\u6301\u7eed\u7684\u6750\u6599\u5f00\u53d1\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

        \u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\uff1a\u4e86\u89e3\u8fd9\u4e9b\u73af\u4fdd\u6750\u6599\u5728\u4e0d\u540c\u6e29\u5ea6\u3001\u538b\u529b\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0\uff0c\u4ee5\u53ca\u5b83\u4eec\u5728\u73b0\u4ee3\u5de5\u7a0b\u4e2d\u7684\u5e94\u7528\u548c\u4f18\u52bf\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[134],"tags":[],"yoast_head":"\n\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027<\/title>\n<meta name=\"description\" content=\"\u53ef\u964d\u89e3\u6750\u6599\u7684\u70ed\u529b\u5b66\u7279\u6027\uff1a\u4e86\u89e3\u8fd9\u4e9b\u73af\u4fdd\u6750\u6599\u5728\u4e0d\u540c\u6e29\u5ea6\u3001\u538b\u529b\u6761\u4ef6\u4e0b\u7684\u6027\u80fd\u8868\u73b0\uff0c\u4ee5\u53ca\u5b83\u4eec\u5728\u73b0\u4ee3\u5de5\u7a0b\u4e2d\u7684\u5e94\u7528\u548c\u4f18\u52bf\u3002\" \/>\n<meta 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