{"id":742540,"date":"2024-10-04T04:34:14","date_gmt":"2024-10-04T03:34:14","guid":{"rendered":"https:\/\/www.thermal-engineering.org\/?p=742540"},"modified":"2024-10-04T04:34:14","modified_gmt":"2024-10-04T03:34:14","slug":"%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6","status":"publish","type":"post","link":"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6\/","title":{"rendered":"\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66"},"content":{"rendered":"<p class=\"sidekick\">\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\uff1a\u6df1\u5165\u89e3\u6790\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u70ed\u80fd\u7684\u8f6c\u6362\u4e0e\u5e73\u8861\uff0c\u63ed\u793a\u5176\u5e94\u7528\u4e2d\u7684\u8282\u80fd\u539f\u7406\uff0c\u52a9\u60a8\u638c\u63e1\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60\u7684\u6838\u5fc3\u6280\u672f\u3002<\/p>\n<p><img src=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/07\/\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66.png\" alt=\"\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\" style=\"display: block; margin-left: auto; margin-right: auto;\"\/><\/p>\n<h2>\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66<\/h2>\n<p>\u70ed\u529b\u5b66\u662f\u7814\u7a76\u80fd\u91cf\u8f6c\u5316\u548c\u4f20\u9012\u7684\u79d1\u5b66\uff0c\u800c\u7535\u5316\u5b66\u70ed\u529b\u5b66\u5219\u662f\u7814\u7a76\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u80fd\u91cf\u7684\u53d8\u5316\u3002\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\uff0c\u5316\u5b66\u80fd\u8f6c\u53d8\u4e3a\u7535\u80fd\uff0c\u6216\u8005\u7535\u80fd\u8f6c\u53d8\u4e3a\u5316\u5b66\u80fd\uff0c\u8fd9\u4e9b\u80fd\u91cf\u8f6c\u6362\u9075\u5faa\u70ed\u529b\u5b66\u5b9a\u5f8b\u3002<\/p>\n<h2>\u57fa\u7840\u6982\u5ff5<\/h2>\n<ul>\n<li><b>\u5409\u5e03\u65af\u81ea\u7531\u80fd (Gibbs Free Energy)\uff1a<\/b> \u8868\u793a\u7cfb\u7edf\u7684\u6700\u5927\u53ef\u7528\u505a\u529f\u7684\u80fd\u91cf\uff0c\u5e38\u7528\u7b26\u53f7 G \u8868\u793a\u3002\u7535\u5316\u5b66\u53cd\u5e94\u7684\u9a71\u52a8\u529b\u53ef\u4ee5\u7528\u53d8\u5316\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd \u0394G \u6765\u8868\u793a\u3002<\/li>\n<li><b>\u7535\u6c60\u7535\u52a8\u52bf (Electromotive Force)\uff1a<\/b> \u7535\u52a8\u52bf\uff08\u7b80\u79f0EMF\uff09\uff0c\u4e5f\u53eb\u5f00\u8def\u7535\u538b\uff0c\u662f\u7535\u6c60\u5728\u6ca1\u6709\u7535\u6d41\u6d41\u52a8\u65f6\u7684\u7535\u538b\uff0c\u5e38\u7528\u7b26\u53f7 E \u8868\u793a\u3002<\/li>\n<li><b>\u53cd\u5e94\u70ed (Reaction Heat)\uff1a<\/b> \u5728\u6052\u6e29\u6052\u538b\u6761\u4ef6\u4e0b\uff0c\u53cd\u5e94\u7cfb\u7edf\u5438\u6536\u6216\u91ca\u653e\u7684\u70ed\u91cf\uff0c\u5e38\u7528\u7b26\u53f7 Q \u8868\u793a\u3002<\/li>\n<\/ul>\n<h2>\u70ed\u529b\u5b66\u5b9a\u5f8b\u5e94\u7528<\/h2>\n<p>\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\uff0c\u5409\u5e03\u65af\u81ea\u7531\u80fd\u4e0e\u7535\u6c60\u7535\u52a8\u52bf\u4e4b\u95f4\u5b58\u5728\u5982\u4e0b\u5173\u7cfb\uff1a<\/p>\n<p style=\"text-align:center;\">\u0394G = -nFE<\/p>\n<p>\u5176\u4e2d\uff1a<\/p>\n<ul>\n<li>\u0394G \u4e3a\u5409\u5e03\u65af\u81ea\u7531\u80fd\u53d8\u5316<\/li>\n<li>n \u4e3a\u53cd\u5e94\u4e2d\u8f6c\u79fb\u7684\u7535\u5b50\u6570<\/li>\n<li>F \u4e3a\u6cd5\u62c9\u7b2c\u5e38\u6570\uff0c\u7ea6\u7b49\u4e8e 96485 C\/mol<\/li>\n<li>E \u4e3a\u7535\u52a8\u52bf<\/li>\n<\/ul>\n<p>\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u5982\u679c \u0394G < 0\uff0c\u5219\u53cd\u5e94\u662f\u81ea\u53d1\u7684\uff1b\u5982\u679c \u0394G > 0\uff0c\u5219\u53cd\u5e94\u662f\u975e\u81ea\u53d1\u7684\u3002\u4e3a\u4e86\u7406\u89e3\u7535\u6c60\u7684\u6548\u7387\uff0c\u53ef\u4ee5\u4ece\u5176 EMF \u548c\u5b9e\u9645\u5de5\u4f5c\u6761\u4ef6\u4e0b\u7684\u7535\u538b\u6765\u8fdb\u884c\u5206\u6790\u3002<\/p>\n<h2>\u70ed\u529b\u5b66\u7b2c\u4e8c\u5b9a\u5f8b<\/h2>\n<p>\u70ed\u529b\u5b66\u7b2c\u4e8c\u5b9a\u5f8b\u6307\u51fa\uff0c\u5c01\u95ed\u7cfb\u7edf\u7684\u71b5\u603b\u662f\u4e0d\u51cf\u5c11\u7684\uff0c\u5373 \u0394S \u2265 0\u3002\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\uff0c\u71b5\u53d8 \u0394S \u4e5f\u662f\u4e00\u4e2a\u5173\u952e\u56e0\u7d20\u3002\u6839\u636e\u70ed\u529b\u5b66\u5173\u7cfb\u5f0f\uff1a<\/p>\n<p style=\"text-align:center;\">\u0394G = \u0394H &#8211; T\u0394S<\/p>\n<p>\u5176\u4e2d\uff1a<\/p>\n<ul>\n<li>\u0394H \u4e3a\u7113\u53d8<\/li>\n<li>\u0394S \u4e3a\u71b5\u53d8<\/li>\n<li>T \u4e3a\u7edd\u5bf9\u6e29\u5ea6\uff08\u5355\u4f4d\uff1a\u5f00\u5c14\u6587\uff09<\/li>\n<\/ul>\n<p>\u901a\u8fc7\u5bf9 \u0394H \u548c \u0394S \u7684\u6d4b\u91cf\uff0c\u53ef\u4ee5\u66f4\u5168\u9762\u5730\u7406\u89e3\u7535\u5316\u5b66\u53cd\u5e94\u7684\u80fd\u91cf\u53d8\u5316\u3002<\/p>\n<h2>\u5b9e\u9645\u5e94\u7528<\/h2>\n<p>\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u7535\u5316\u5b66\u70ed\u529b\u5b66\u7528\u4e8e\u591a\u4e2a\u9886\u57df\u3002\u4f8b\u5982\uff1a<\/p>\n<ul>\n<li><b>\u7535\u6c60\u8bbe\u8ba1\uff1a<\/b> \u901a\u8fc7\u7406\u89e3\u53cd\u5e94\u7684\u70ed\u529b\u5b66\u53c2\u6570\uff0c\u53ef\u4ee5\u8bbe\u8ba1\u51fa\u66f4\u9ad8\u6548\u3001\u66f4\u7a33\u5b9a\u7684\u7535\u6c60\u3002<\/li>\n<li><b>\u7535\u9540\u5de5\u827a\uff1a<\/b> \u8c03\u6574\u7535\u5316\u5b66\u53c2\u6570\uff0c\u4f18\u5316\u7535\u9540\u7684\u8d28\u91cf\u548c\u6548\u7387\u3002<\/li>\n<li><b>\u71c3\u6599\u7535\u6c60\uff1a<\/b> \u5206\u6790\u53cd\u5e94\u4e2d\u7684\u70ed\u529b\u5b66\u8fc7\u7a0b\uff0c\u53ef\u4ee5\u63d0\u9ad8\u71c3\u6599\u7535\u6c60\u7684\u6548\u7387\u548c\u5bff\u547d\u3002<\/li>\n<\/ul>\n<p>\u4e86\u89e3\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\u662f\u4f18\u5316\u5404\u79cd\u7535\u5316\u5b66\u7cfb\u7edf\u7684\u57fa\u7840\u3002\u901a\u8fc7\u5bf9\u5409\u5e03\u65af\u81ea\u7531\u80fd\u3001\u7535\u52a8\u52bf\u7b49\u53c2\u6570\u7684\u5206\u6790\uff0c\u6211\u4eec\u53ef\u4ee5\u8bbe\u8ba1\u548c\u6539\u8fdb\u7535\u5316\u5b66\u88c5\u7f6e\uff0c\u4f7f\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u8868\u73b0\u66f4\u4f73\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\uff1a\u6df1\u5165\u89e3\u6790\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u70ed\u80fd\u7684\u8f6c\u6362\u4e0e\u5e73\u8861\uff0c\u63ed\u793a\u5176\u5e94\u7528\u4e2d\u7684\u8282\u80fd\u539f\u7406\uff0c\u52a9\u60a8\u638c\u63e1\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60\u7684\u6838\u5fc3\u6280\u672f\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[134],"tags":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v15.4 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66<\/title>\n<meta name=\"description\" content=\"\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\uff1a\u6df1\u5165\u89e3\u6790\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u70ed\u80fd\u7684\u8f6c\u6362\u4e0e\u5e73\u8861\uff0c\u63ed\u793a\u5176\u5e94\u7528\u4e2d\u7684\u8282\u80fd\u539f\u7406\uff0c\u52a9\u60a8\u638c\u63e1\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60\u7684\u6838\u5fc3\u6280\u672f\u3002\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.thermal-engineering.org\/zh-hans\/\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\/\" \/>\n<meta property=\"og:locale\" content=\"zh_CN\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\" \/>\n<meta property=\"og:description\" content=\"\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\uff1a\u6df1\u5165\u89e3\u6790\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u70ed\u80fd\u7684\u8f6c\u6362\u4e0e\u5e73\u8861\uff0c\u63ed\u793a\u5176\u5e94\u7528\u4e2d\u7684\u8282\u80fd\u539f\u7406\uff0c\u52a9\u60a8\u638c\u63e1\u7535\u6c60\u548c\u71c3\u6599\u7535\u6c60\u7684\u6838\u5fc3\u6280\u672f\u3002\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.thermal-engineering.org\/zh-hans\/\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66\/\" \/>\n<meta property=\"og:site_name\" content=\"Thermal Engineering\" \/>\n<meta property=\"article:published_time\" content=\"2024-10-04T03:34:14+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/07\/\u7535\u5316\u5b66\u53cd\u5e94\u7684\u70ed\u529b\u5b66.png\" \/>\n<meta name=\"twitter:card\" content=\"summary\" \/>\n<meta name=\"twitter:label1\" content=\"\u4f5c\u8005\">\n\t<meta name=\"twitter:data1\" content=\"Nick Connor\">\n\t<meta name=\"twitter:label2\" content=\"\u9884\u8ba1\u9605\u8bfb\u65f6\u95f4\">\n\t<meta name=\"twitter:data2\" content=\"0\u5206\">\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.thermal-engineering.org\/fr\/#website\",\"url\":\"https:\/\/www.thermal-engineering.org\/fr\/\",\"name\":\"Thermal Engineering\",\"description\":\"\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":\"https:\/\/www.thermal-engineering.org\/fr\/?s={search_term_string}\",\"query-input\":\"required name=search_term_string\"}],\"inLanguage\":\"zh-CN\"},{\"@type\":\"ImageObject\",\"@id\":\"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6\/#primaryimage\",\"inLanguage\":\"zh-CN\",\"url\":\"https:\/\/www.thermal-engineering.org\/wp-content\/uploads\/2024\/07\/\\u7535\\u5316\\u5b66\\u53cd\\u5e94\\u7684\\u70ed\\u529b\\u5b66.png\",\"width\":1000,\"height\":1000,\"caption\":\"\\u7535\\u5316\\u5b66\\u53cd\\u5e94\\u7684\\u70ed\\u529b\\u5b66\"},{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6\/#webpage\",\"url\":\"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6\/\",\"name\":\"\\u7535\\u5316\\u5b66\\u53cd\\u5e94\\u7684\\u70ed\\u529b\\u5b66\",\"isPartOf\":{\"@id\":\"https:\/\/www.thermal-engineering.org\/fr\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6\/#primaryimage\"},\"datePublished\":\"2024-10-04T03:34:14+00:00\",\"dateModified\":\"2024-10-04T03:34:14+00:00\",\"author\":{\"@id\":\"https:\/\/www.thermal-engineering.org\/fr\/#\/schema\/person\/e8c544db9afedaec8574d6464f9398bb\"},\"description\":\"\\u7535\\u5316\\u5b66\\u53cd\\u5e94\\u7684\\u70ed\\u529b\\u5b66\\uff1a\\u6df1\\u5165\\u89e3\\u6790\\u7535\\u5316\\u5b66\\u8fc7\\u7a0b\\u4e2d\\u70ed\\u80fd\\u7684\\u8f6c\\u6362\\u4e0e\\u5e73\\u8861\\uff0c\\u63ed\\u793a\\u5176\\u5e94\\u7528\\u4e2d\\u7684\\u8282\\u80fd\\u539f\\u7406\\uff0c\\u52a9\\u60a8\\u638c\\u63e1\\u7535\\u6c60\\u548c\\u71c3\\u6599\\u7535\\u6c60\\u7684\\u6838\\u5fc3\\u6280\\u672f\\u3002\",\"inLanguage\":\"zh-CN\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.thermal-engineering.org\/zh-hans\/%e7%94%b5%e5%8c%96%e5%ad%a6%e5%8f%8d%e5%ba%94%e7%9a%84%e7%83%ad%e5%8a%9b%e5%ad%a6\/\"]}]},{\"@type\":\"Person\",\"@id\":\"https:\/\/www.thermal-engineering.org\/fr\/#\/schema\/person\/e8c544db9afedaec8574d6464f9398bb\",\"name\":\"Nick Connor\",\"image\":{\"@type\":\"ImageObject\",\"@id\":\"https:\/\/www.thermal-engineering.org\/fr\/#personlogo\",\"inLanguage\":\"zh-CN\",\"url\":\"https:\/\/secure.gravatar.com\/avatar\/84c0dec310b44b65da29dc9df6925239?s=96&d=mm&r=g\",\"caption\":\"Nick Connor\"}}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","_links":{"self":[{"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/posts\/742540"}],"collection":[{"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/comments?post=742540"}],"version-history":[{"count":0,"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/posts\/742540\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/media?parent=742540"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/categories?post=742540"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.thermal-engineering.org\/zh-hans\/wp-json\/wp\/v2\/tags?post=742540"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}