Cyclic Process
A process that eventually returns a system to its initial state is called a cyclic process. At the conclusion of a cycle, all the properties have the same value they had at the beginning. For such a process, the final state is the same as the initial state, and so the total internal energy change must be zero. Steam (water) that circulates through a closed cooling loop undergoes a cycle. The first law of thermodynamics is then:
dEint = 0, dQ = dW
Thus, the net work done during the process must exactly equal the net amount of energy transferred as heat. It must be noted, according to the second law of thermodynamics, not all heat provided to a cycle can be transformed into an equal amount of work, some heat rejection must take place.
Example of Cyclic Process – Brayton Cycle
Let assume the ideal Brayton cycle that describes the workings of a constant pressure heat engine. Modern gas turbine engines and airbreathing jet engines also follow the Brayton cycle. This cycle consist of four thermodynamic processes:
Ideal Brayton cycle consist of four thermodynamic processes. Two isentropic processes and two isobaric processes.
- isentropic compression – ambient air is drawn into the compressor, where it is pressurized (1 → 2). The work required for the compressor is given by WC = H2 – H1.
- isobaric heat addition – the compressed air then runs through a combustion chamber, where fuel is burned and air or another medium is heated (2 → 3). It is a constant-pressure process, since the chamber is open to flow in and out. The net heat added is given by Qadd = H3 – H2
- isentropic expansion – the heated, pressurized air then expands on turbine, gives up its energy. The work done by turbine is given by WT = H4 – H3
- isobaric heat rejection – the residual heat must be rejected in order to close the cycle. The net heat rejected is given by Qre = H4 – H1
As can be seen, we can describe and calculate (e.g. thermal efficiency) such cycles (similarly for Rankine cycle) using enthalpies.
See also: Thermal Efficiency of Brayton Cycle
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